Excluded Volume, Free Volume and Hard Sphere Packing

The following sections are included:

• Excluded Volume and Packing Problems

• Accessible Configuration Space

• Experiments on Random Packing Models

• Origins of Method of Molecular Dynamics

• Free-Volume Approximation

• Free Volume and Entropically Driven Freezing Transition

• Building on Hard Sphere Equation of State: the Model of Longuet–Higgins and Widom

• Hard-Particle Fluid Equation of State Using Nearest-Neighbour Correlations

• Free Volume Revisited in Hard Sphere Fluid

• Hard Particles in Low Dimensions

• Equation of State of Hard-Body Fluids

• Hard Sphere Fluid in Narrow Cylindrical Pores