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Pyrene containing liquid crystalline asymmetric phthalocyanines and their composite materials with single-walled carbon nanotubes

Esra Nur Kaya

Gebze Technical University, Department of Chemistry, Gebze, Kocaeli 41400, Turkey

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Maxim S. Polyakov

Nikolaev Institutes of Inorganic Chemistry SB RAS, Lavrentiev Pr. 3, Novosibirsk 630090, Russia

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Tamara V. Basova

Nikolaev Institutes of Inorganic Chemistry SB RAS, Lavrentiev Pr. 3, Novosibirsk 630090, Russia

Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia

E-mail Address: basova@niic.nsc.ru

Correspondence to: Tamara Basova, Nikolaev Institutes of Inorganic Chemistry SB RAS, Lavrentiev Pr. 3, Novosibirsk, Russia. tel.: +7 383 3308957; fax: +7 383 3309489

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Mahmut Durmuş

Gebze Technical University, Department of Chemistry, Gebze, Kocaeli 41400, Turkey

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, and

Aseel Hassan

Material and Engineering Research Institute, Sheffield Hallam University, Sheffield, UK

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https://doi.org/10.1142/S1088424618500025Cited by:8 (Source: Crossref)

Abstract

In the present work we have studied the dispersion of single-walled carbon nanotubes in liquid crystalline asymmetrically substituted phthalocyanines (MPc, where M $=$ Cu, Co, and 2H) bearing one pyrene and six polyoxy groups as side chains. The influence of single-walled carbon nanotubes on the phase behavior of MPcs was investigated using X-ray diffraction, polarized optical microscopy and differential scanning calorimetry. It was demonstrated that the incorporation of small amounts of single-walled carbon nanotubes ( $\leq$ 1 wt.%) does not alter the MPc mesophases. The structural features and the sensor response of composite thin films of MPc with single-walled carbon nanotubes to ammonia vapor (10–50 ppm) was studied and compared with those of the films of pure MPc derivatives.

Dedicated to Professor Kazuchika Ohta on the occasion of his retirement

Keywords:

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