No Access

An LDI-TOF and ESI mass spectrometry study of a series of β-substituted cationic metalloporphyrins

Department of Medicine, National Jewish Medical and Research Center, Denver, CO 80206, USA

Corresponding author, Department of Medicine, National Jewish Medical and Research Center, 1400 Jackson street, Denver, CO 80206, USA.

Search for more papers by this author

N. SRINIVASAN

Department of Chemistry, North Carolina State University, Raleigh, NC 27695, USA

Search for more papers by this author

C. A. HANEY

Department of Chemistry, North Carolina State University, Raleigh, NC 27695, USA

Search for more papers by this author

, and

R. D. STEVENS

Department of Pediatrics, Duke University Medical Center, Durham, NC 27710, USA

Search for more papers by this author

https://doi.org/10.1002/jpp.354Cited by:13 (Source: Crossref)

Abstract

A series of β-halogenated cationic metalloporphyrins were analyzed by LDI-TOF and ESI-MS. Although LDI-TOFMS reveals to be a good tool for the characterization of this family of metal-complexes, including the redox state of the metal, ESI-MS indicates in addition the relative tendency of such metal-complexes to be reduced.

Keywords:

Most comprehensive & up-to-date research on PORPHYRINS
Handbook of Porphyrin Science now available in 46 volumes

References

B. Meunier, Chem. Rev. 92, 1411 (1992), DOI: 10.1021/cr00014a008. Web of Science, Google Scholar
M. R. Hamblin and E. L. Newman, J. Photochem. Photobiol. B: Biol. 23, 3 (1994), DOI: 10.1016/S1011-1344(94)80018-9. Web of Science, Google Scholar
K. M. Faulkner, S. I. Liochev and I. Fridovich, J. Biol. Chem. 269, 23471 (1994). Web of Science, Google Scholar
I. Batinic-Haberleet al., Arch. Biochem. Biophys. 343, 225 (1997), DOI: 10.1006/abbi.1997.0157. Web of Science, Google Scholar
I. Batinic-Haberleet al., J. Biol. Chem. 273, 24521 (1998), DOI: 10.1074/jbc.273.38.24521. Web of Science, Google Scholar
R. Kachadourian, I. Batinic-Haberle and I. Fridovich, Inorg. Chem. 38, 391 (1999), DOI: 10.1021/ic9808854. Web of Science, Google Scholar
I. Batinic-Haberleet al., Inorg. Chem. 38, 4011 (1999), DOI: 10.1021/ic990118k. Web of Science, Google Scholar
G. G. Menget al., Can. J. Chem. 72, 2447 (1994), DOI: 10.1139/v94-311. Web of Science, Google Scholar
Y.-C. Lin, L. Lin and Y.-T. Chen, Rapid Commun. Mass Spectrom. 12, 317 (1998). Web of Science, Google Scholar
S.-Q. Liuet al., Rapid Commun. Mass Spectrom. 13, 2034 (1999). Web of Science, Google Scholar
E. Tarnaudet al., Org. Mass Spectrom. 28, 132 (1999), DOI: 10.1002/oms.1210280213. Web of Science, Google Scholar
P. Bigeyet al., Bull. Soc. Chim. Fr. 133, 679 (1996). Google Scholar
I. Batinic-Haberle, R. D. Stevens and I. Fridovich, J. Porphyrins Phthalocyanines 4, 217 (2000). Link, Google Scholar
V. E. Vandell and P. A. Limbach, J. Mass Spectrom. 33, 212 (1998). Web of Science, Google Scholar
T. A. Rao and B. G. Maiya, Inorg. Chem. 35, 4829 (1996), DOI: 10.1021/ic9513200. Web of Science, Google Scholar
F. M. Rubinoet al., Org. Mass Spectrom. 26, 161 (1991), DOI: 10.1002/oms.1210260311. Web of Science, Google Scholar
E. Forestet al., Org. Mass Spectrom. 24, 197 (1989), DOI: 10.1002/oms.1210240313. Web of Science, Google Scholar
E. Forestet al., Org. Mass Spectrom. 22, 45 (1987), DOI: 10.1002/oms.1210220112. Web of Science, Google Scholar
For a comparative study of uncharged porphyrin oligomers using several MS techniques including FAB, MALDI and ESI see: Siegel MM, Tabei K, Tsao R, Pastel MJ, Pandey RK, Berkenkamp S, Hillenkamp F, Hillenkamp F, de Vries MS. J. Mass Spectrom. 1999; 34: 661 . Google Scholar
N. Srinivasanet al., J. Porphyrins Phthalocyanines 3, 283 (1999). Link, Web of Science, Google Scholar
For a FAB-MS study of β-substituted uncharged porphyrins see: Boschi T, D'Arcangelo G, Tagliatesta P. J. Chem. Res., Synop. 1995; 326 . Google Scholar
G. Wang and R. B. Cole, J. Am. Soc. Mass Spectrom. 7, 1050 (1996), DOI: 10.1016/1044-0305(96)00051-7. Web of Science, Google Scholar