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10: Voltammetry in Weakly Supported Media: Migration and Other Effects

      https://doi.org/10.1142/9781786345271_0010Cited by:0 (Source: Crossref)
      Abstract:

      Previously we have considered mass transport in solution resulting from either diffusion (Chapter 3) and/or convection (Chapter 8). In this chapter we explore the movement of ions resulting from a non-uniform electrical potential, ϕ. That is when an electrical field, or potential gradient is present where

      electricalfield=ϕ,    (10.1)
      or, in one dimension, x,
      electricalfield=ϕx.    (10.2)
      Such fields drive the movement of ions in the direction of the field or against it according to their charge.