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Trial function optimization for excited states of van der Waals clusters

    https://doi.org/10.1142/9789812775696_0009Cited by:1 (Source: Crossref)
    Abstract:

    A method is introduced to optimize excited state trial wavefunctions. The method is applied to ground and vibrationally excited states of bosonic van der Waals clusters of upto seven particles. Employing optimized trial wave functions with three-body correlations, we use correlation function Monte Carlo to estimate the corresponding excited state energies.