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Effective and Mild Ionic Hydrogenation of Carbon Monoxide, Carbon Dioxide, Methyl Alcohol, Formic Acid, Carbonyl Sulfide and Carbon Disulfide to Methane with Sodium Borohydride/Trifluoromethanesulfonic (triflic) Acid
Synthetic Methods and Reactions. 163. For Part 162 see: Olah, G. A., Wu, A., Bagno, A., Prakash, G. K. S. Synlett 1990, 596.
https://doi.org/10.1142/9789812791405_0175Cited by:0 (Source: Crossref)
Abstract:
Carbon monoxide, carbon dioxide, methyl alcohol, formic acid, carbonyl sulfide and carbon disulfide are reduced to methane by ionic hydrogenation using sodium borohydride and superacidic trifluoromethanesulfonic acid. Experimental details are given and the mechanism is discussed.
Dedication: Dedicated to Professor Ivar Ugi on the occasion of his 60th birthday.
