Surface Specific Heat of an Isotropic Solid at Low Temperatures
Based on dissertations presented to the Graduate School of Yale University in partial fulfillment of the requirements for the degree of Doctor of Philosophy in 1955 (RM) and 1959 (MD).
The effect of realistic boundary conditions on the computation of the specific heat of an isotropic solid at low temperatures is investigated. Two cases are considered: the surface free of stress and the surface rigidly clamped. The first of these is the one of physical interest. For both cases a term in the specific heat arises which is proportional to the surface area and to T2 and appreciably higher than Montroll's result in the case of the free solid. The effect of approximations introduced during the computation is estimated. Available experimental data are not adequate for a critical test of the theory.
