INDIVIDUAL NONASSOCIATED POLAR LIQUIDS

The following sections are included:

• Liquid Fluoromethane CH₃F

• The Rotational Cell Model (RCM)

• Liquid Trifluoromethane CHF₃

  • Application of the CR Model with Fitted Parameters

  • Application of the CR Model / Rotational Cell Model

• Prediction of the Critical Temperature

  • Determination of T_cr from the Condition, Imposed on the Libration Amplitude

  • Determination of T_cr from the Minimum τ_D(τ) Condition

  • On the Nature of Liquid → Solid Phase Transition

• Molecular Interpretation of the “Rotational” Lifetime τ in the Light of the Debye Rotational Diffusion Theory

• Relation of the Potential Welldepth to Dielectric Spectra

  • Dielectric Spectra and the Potential Welldepth

  • Dependence of the Welldepth on Temperature

• The Polarizability A"(v) Spectra

• Distortion of the Cole-Cole Diagram due to Micro Heterogeneity

• Isotropic Potential and the Self-Diffusion Coefficient