Resonant Two-Photon Ionization Studies of C6H6-Xn Clusters
The following sections are included:
Introduction
Experimental Methods
Rotational band contour analysis
Symmetry reduction as a vibronic level structural probe
Frequency shifts and cluster ion fragmentation
Dispersed fluorescence scans
Fluorescence lifetimes
Intermolecular vibrational structure
Results on the C6H6-X Complexes
C6H6-Ar and C6H6-(Ar)2
C6H6-HCl
C6H6-CHCl3
C6H6-CCl4
C6H6-H2O
C6-H6CH3OH
The π Hydrogen Bond
MMC Calculations on C6H6-HCl and C6H6-H2O
OPLS Calculations on C6H6-CHCl3 and C6H6-CH3OH
Some Comments on the π Hydrogen Bond
Larger C6H-Xn Clusters
C6H6-(H2O)n Clusters, n = 2-5
C6H6-(H2O)2
C6H6-(H2O)3-5
C6H6-(CH3OH)m Clusters, m = 2-5
C6H6-(H2O)n (CH3OH)m, (n + m) ≤ 4
MMC and OPLS calculations on BWn, BMm and BWnMm
Concluding Remarks
Acknowledgements
References