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ON THE OPTICAL CHARACTERISTICS OF CdS THIN FILMS DEPOSITED BY QUASI-CLOSED VOLUME TECHNIQUE

    https://doi.org/10.1142/S0217979204024616Cited by:7 (Source: Crossref)

    Cadmium sulfide (CdS) thin films (d=0.15–1.15 μm) were deposited onto glass substrates by the quasi-closed volume technique under vacuum. The investigations shown that the films are polycrystalline and have a hexagonal structure. It was experimentally established that the films with stable structure can be obtained if they are submitted to a heat treatment, consisting of several succesive heating/cooling cycles within a given temperature range (ΔT=300–600 K), the temperature dependence of the electrical conductivity becomes reversible. For heat-treated samples, the values of thermal activation energy calculated from the temperature dependence of the electrical conductivity, ranged between 2.30–2.45 eV. The spectral dependences of the transmission and absorption coefficients were studied in the range 500–1400 nm. The influence of heat treatment on the shape of the absorption spectra and dispersion index of refraction is studied for samples with different thickness. Optical energy gap, calculated from the absorption spectra was in the range 2.30–2.5 eV.

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