STRUCTURAL CHANGES OF Ni-DOPED YBCO AT DIFFERENT TEMPERATURE
Abstract
In YBa2Cu3-xNixOy at about 480°C all the samples show a tetragonal phase. Comparing the structural changes at 480°C with those at room temperature, the bond lengths such as Cu(1)-O(4) and Cu(2)-O(4) vary regularly with Ni-content increasing at room temperature, but not at high temperature. It suggests that there is a close correlation between structural changes and superconductivity in this system. The difference of orthorhombic- tetragonal phase -transition is also discussed between undoped YBCO and Ni-doped YBCO at high temperature.
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