SYNTHESIS OF Ru1-xSbxSr2(Eu0.7Ce0.3)2Cu2O10-δ AND THEIR MAGNETIC AND TRANSPORT PROPERTIES
Abstract
Ru1-xSbxSr2(Eu0.7Ce0.3)2Cu2O10-δ systems were prepared by conventional solid state reaction method. The structural analysis was investigated using X-ray diffraction. Electrical resistivity, Hall effect and magnetic susceptibility measurements on Ru:1222 doped with Sb are presented, together with results in the temperature range 5–300 K. Transition temperature decreases from 43 K for x = 0.00 to 20 K for x = 0.06 Sb. This may be due to a distortion of RuO6 octahedral, which is responsible of the increase in hole localization. The Hall effect anomalous decreases below Tmagnetic which may be explained within a simple two-band model by a transition from localized to more itinerant behavior in the RuO2 layer at Tmagnetic. The behavior of magnetic susceptibility is caused by an antisymmetric exchange coupling of the Dzyaloshinsky–Morya type between neighboring Ru moments.
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