ENHANCED NUCLEATION AND SMOOTHNESS OF NANOCRYSTALLINE DIAMOND FILMS VIA W-C GRADIENT INTERLAYER
Abstract
CVD diamond coating was deposited on to 13%wt. Co-containing tungsten cemented carbide surfaces using a hot filament chemical vapor deposition (HFCVD) to improve wear properties and performance of WC-13%wt.Co. Prior to the deposition of the diamond films, a W-C gradient intermediate layer had been sputtered on WC-13%wt.Co. The surface and cross-section morphology, phase transformation, and grain size distribution of the samples were investigated by means of field emission scanning electron microscope (SEM), X-ray diffractometer (XRD), and atomic force microscope (AFM), respectively. The results show that W-C gradient intermediate layers can effectively reduce the diffusion of Co in cemented carbide substrates during diamond deposition process, resulting high nucleation density and ultra smooth nanocrystalline diamond films.
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