Search
This Journal
This Journal
Anywhere
Quick Search in Journals
Enter words / phrases / DOI / ISBN / keywords / authors / etc
Access type:Only show content I have full access toOnly show Open Access
Advanced Search
0 My Cart
Sign in
Institutional Access

System Upgrade on Tue, May 28th, 2024 at 2am (EDT)

Existing users will be able to log into the site and access content. However, E-commerce and registration of new users may not be available for up to 12 hours.
For online purchase, please visit us again. Contact us at customercare@wspc.com for any enquiries.

SPECIAL ISSUE: Proceedings of Advances in Functional Materials; 8–12 June 2009, Sichuan, China and 15–18 June 2009, Jinju, KoreaNo Access

HYDROGEN BONDING CHARACTERISTICS OF CRYSTALLINE WATER IN INORGANIC CRYSTALS

State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

Search for more papers by this author

,

State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

Search for more papers by this author

, and

State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

Corresponding author.

Search for more papers by this author

https://doi.org/10.1142/S021798490902206XCited by:2 (Source: Crossref)

Abstract

From the chemical bond viewpoint, the microscopic characterstatics of hydrogen bonds in M_i—OH₂⋯O (M is the metal cation coordinated to water molecule and i is the number of M) systems were comprehensively studied. It is shown that the original O—OH and H⋯O bond lengths of each hydrogen bonding system are evidently influenced by the crystalline environment and strongly dependent on the corresponding average bond lengths of each system, and . Furthermore, the hydrogen bonding capability of water molecules coordinated to various metal cations was properly estimated and found to be related to the ionic electronegativities of these metal cations. The current work provides a useful route to calculating hydrogen bond valences within reasonable accuracy and sheds light on the rational utilization of hydrogen bonds in crystal design.

Keywords:

References

C. Yan and D. Xue, Funct. Mater. Lett. 1, 37 (2008), DOI: 10.1142/S1793604708000083. Link, Web of Science, Google Scholar
C. Yanet al., Nanoscale Res. Lett. 3, 473 (2008), DOI: 10.1007/s11671-008-9193-6. Crossref, Web of Science, ADS, Google Scholar
Y. Zhang and H. Zeng, Funct. Mater. Lett. 1, 43 (2008), DOI: 10.1142/S1793604708000095. Link, Web of Science, Google Scholar
S. Yin, B. Liu and T. Sato, Funct. Mater. Lett. 1, 173 (2008), DOI: 10.1142/S1793604708000319. Link, Web of Science, Google Scholar
Y. Zhu, Funct. Mater. Lett. 1, 239 (2008), DOI: 10.1142/S1793604708000435. Link, Web of Science, Google Scholar
D. Xue and S. Zhang, Physica B 262, 78 (1999), DOI: 10.1016/S0921-4526(98)00465-7. Crossref, Web of Science, ADS, Google Scholar
K. Li and D. Xue, J. Phys. Chem. A 110, 11332 (2006), DOI: 10.1021/jp062886k. Crossref, Web of Science, Google Scholar
K. Li, X. Wang and D. Xue, J. Phys. Chem. A 112, 7894 (2008), DOI: 10.1021/jp8012738. Crossref, Web of Science, Google Scholar
K. Liet al., Phys. Rev. Lett. 100, (2008). Google Scholar
D. Xu, D. Xue and H. Ratajczak, J. Mol. Struct. 740, 37 (2005), DOI: 10.1016/j.molstruc.2005.01.016. Crossref, Web of Science, ADS, Google Scholar
X. Ren, D. Xu and D. Xue, J. Cryst. Growth 310, 2005 (2008), DOI: 10.1016/j.jcrysgro.2007.11.008. Crossref, Web of Science, Google Scholar
D. Xu and D. Xue, J. Cryst. Growth 310, 1385 (2008), DOI: 10.1016/j.jcrysgro.2007.12.008. Crossref, Web of Science, ADS, Google Scholar
D. Xue and S. Zhang, Chem. Phys. Lett. 301, 449 (1999), DOI: 10.1016/S0009-2614(99)00055-X. Crossref, Web of Science, ADS, Google Scholar
D. Xueet al., Bull. Pol. Acad. Sci. Chem. 50, 289 (2002). Google Scholar
K. Beckenkamp and H. D. Lutz, J. Mol. Struct. 270, 393 (1992), DOI: 10.1016/0022-2860(92)85042-F. Crossref, Web of Science, ADS, Google Scholar
E. Libowitzky, Monatsh. Chem. 130, 1047 (1999). Crossref, Web of Science, Google Scholar
I. D. Brown , The Chemical Bond in Inorganic Chemistry: the Bond Valence Model ( Oxford University Press , 2002 ) . Google Scholar
N. E. Brese and M. O'Keeffe, Acta Crystallogr., Sect. B 47, 192 (1991), DOI: 10.1107/S0108768190011041. Crossref, Web of Science, ADS, Google Scholar
H. Alig, J. Losel and M. Tromel, Z. Kristallogr. 209, 18 (1994). Crossref, Web of Science, Google Scholar
T. Steiner and W. Saenger, Acta Crystallogr., Sect. B 50, 348 (1994), DOI: 10.1107/S0108768193011966. Crossref, Web of Science, ADS, Google Scholar
D. Yu, D. Xue and H. Ratajczak, Physica B 371, 170 (2006), DOI: 10.1016/j.physb.2005.10.128. Crossref, Web of Science, ADS, Google Scholar
D. Yu, D. Xue and H. Ratajczak, J. Mol. Struct. 783, 210 (2006), DOI: 10.1016/j.molstruc.2005.08.022. Crossref, Web of Science, ADS, Google Scholar
D. Yu, D. Xue and H. Ratajczak, J. Mol. Struct. 792, 280 (2006). Web of Science, ADS, Google Scholar
H. D. Lutzet al., J. Mol. Struct. 351, 205 (1995), DOI: 10.1016/0022-2860(95)08813-B. Crossref, Web of Science, ADS, Google Scholar
R. Mortel and H. D. Lutz, J. Mol. Struct. 648, 171 (2003), DOI: 10.1016/S0022-2860(02)00713-5. Crossref, Web of Science, ADS, Google Scholar
B. R. Bickmoreet al., J. Phys. Chem. A 113, 1847 (2009), DOI: 10.1021/jp810364t. Crossref, Web of Science, Google Scholar
Inorganic Crystal Structure Database, Version: 2004-1 . Google Scholar

Journal cover image

Vol. 23, No. 31n32

Metrics

Downloaded 23 times

History

Keywords