Research PapersNo Access

CALCULATION OF THE MOLAR VOLUME IN THE SOLID AND LIQUID PHASES OF CCl₄

H. YURTSEVEN

Department of Physics, Middle East Technical University, 06531 Ankara, Turkey

Search for more papers by this author

and

D. KAVRUK

Department of Physics, Middle East Technical University, 06531 Ankara, Turkey

Search for more papers by this author

https://doi.org/10.1142/S0217984910022184Cited by:3 (Source: Crossref)

Abstract

The molar volume of carbon tetrachloride is calculated as functions of temperature and pressure close to the melting point. By analyzing the experimental data for the pressure dependence of the thermal expansivity according to a power-law formula, the molar volume is calculated for the solid and liquid phases of this molecular organic compound.

Our calculations show that the molar volume of the solid phase increases almost linearly as the temperature and pressure increase, so that there is no anomalous behavior close to the melting point in CCl₄. In the liquid phase, it does not vary considerably within the given pressure and temperature ranges. Our calculated molar volumes can be compared with measurements for CCl₄ under the given pressure and temperature variations.

Keywords:

References

V. E. Bean and S. D. Wood, J. Chem. Phys. 72, 5838 (1980), DOI: 10.1063/1.439107. Web of Science, ADS, Google Scholar
T. Makita and T. Takagi, Rev. Phys. Chem. Jpn. 38, 41 (1968). Web of Science, Google Scholar
R. Rudman and B. Post, Science 154, 1009 (1966). Web of Science, Google Scholar
J. G. Arentsen and J. C. van Miltenburg, J. Chem. Thermodyn. 4, 789 (1972), DOI: 10.1016/0021-9614(72)90053-5. Web of Science, Google Scholar
Y. Koga and J. A. Morrison, J. Chem. Phys. 62, 3359 (1975), DOI: 10.1063/1.430920. Web of Science, ADS, Google Scholar
J. A. Morrison and E. L. Richards, J. Chem. Thermodyn. 8, 1033 (1976), DOI: 10.1016/0021-9614(76)90134-8. Web of Science, Google Scholar
J. P. Dumas, J. Phys. C 9, L143 (1976), DOI: 10.1088/0022-3719/9/6/002. Web of Science, Google Scholar
G. J. Piermarini and A. B. Braun, J. Chem. Phys. 58, 1974 (1973), DOI: 10.1063/1.1679460. Web of Science, Google Scholar
D. M. Adams and S. K. Sharma, J. Chem. Soc. Dalton Trans. 23, 2424 (1976). Google Scholar
H. Kawamuraet al., Solid State Comm. 102, 501 (1997), DOI: 10.1016/S0038-1098(97)00054-9. Web of Science, ADS, Google Scholar
L. C. Pardoet al., Chem. Phys. Lett. 308, 204 (1999), DOI: 10.1016/S0009-2614(99)00627-2. Web of Science, ADS, Google Scholar
I. Kanesaka, T. Tamura and Y. Akizawa, J. Raman Spectrosc. 30, 69 (1999). Web of Science, ADS, Google Scholar
R. Radhakrishnan, K. E. Gubbins and M. S. Bartkowiak, Phys. Rev. Lett. 89, 076101-1 (2002), DOI: 10.1103/PhysRevLett.89.076101. Google Scholar
Ph. Pruzan, L. T. Minassian and A. Soulard, High Pressure Science and Technology 1, eds. K. D. Timmerhams and M. S. Barber (Plenum, New York, 1979) p. 368. Google Scholar
S. D. Wood and V. E. Bean, High Pressure Science and Technology 22, eds. C. Homan, R. K. MacCrone and E. Whalley (North Holland, New York, 1984) p. 29. Google Scholar
Ph. Pruzan, D. H. Liebenberg and R. L. Mills, J. Phys. Chem. Solids 47, 949 (1986), DOI: 10.1016/0022-3697(86)90107-1. Web of Science, ADS, Google Scholar
J. Timmermans, Physico-Chemical Constants of Pure Organic Compounds, Binary Systems in Concentrated Solutions 4 (Interscience Publishers, New York, 1960) p. 619. Google Scholar
A. Compagner, Physica 72, 115 (1974), DOI: 10.1016/0031-8914(74)90144-X. Web of Science, ADS, Google Scholar
R. J. Speedy, J. Phys. Chem. 86, 3002 (1982), DOI: 10.1021/j100212a038. Web of Science, Google Scholar
L. Li Boyer, Phys. Rev. B 23, 3673 (1981). Web of Science, Google Scholar
D. C. Larsen (ed.), Thermal Expansion (Plenum Press, New York, 1982) p. 131. Google Scholar
R. Lipowsky, Phys. Rev. Lett. 49, 1975 (1982), DOI: 10.1103/PhysRevLett.49.1575. Google Scholar
R. Lipowsky and W. Speth, Phys. Rev. B 28, 3983 (1983), DOI: 10.1103/PhysRevB.28.3983. Web of Science, ADS, Google Scholar