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The role of the spectral matrix effect in the element analysis of biological fluids in ICP-MS

T. K. Nurubeyli

Institute of Physics, ANAS, Baku, AZ-1143, Azerbaijan

E-mail Address: kamilnuri@rambler.ru

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and

Kh. N. Ahmadova

Institute of Physics, ANAS, Baku, AZ-1143, Azerbaijan

Azerbaijan State Oil and Industrial University, Baku AZ-1010, Azerbaijan

E-mail Address: x.khalilova@rambler.ru

Corresponding author.

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https://doi.org/10.1142/S0217984921500949Cited by:2 (Source: Crossref)

Abstract

Elements in whole blood and urine were determined, and the influence of matrix spectral interference on the analysis results was evaluated in search of optimal measurement conditions on the quadrupole mass spectrometer with inductively coupled plasma Agilent 7700 that did not require correction when determining the varied elements in physical properties. The study showed that when using a quadrupole mass spectrometer, the detection limit of gallium in the studied biological fluids (both whole blood and urine) will be determined not by the background content of the element, but by the interfering effect of ions formed by the matrix components of the analyzed samples.

Keywords:

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