Regular ArticlesNo Access

A MANGANESE OXIDE CONTAINED COATING FOR BIODEGRADABLE AZ31B MAGNESIUM ALLOY

TINGTING YAN

Department of Material Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Search for more papers by this author

LILI TAN

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Search for more papers by this author

DANGSHENG XIONG

Department of Material Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Corresponding author.

Search for more papers by this author

BINGCHUN ZHANG

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Search for more papers by this author

, and

KE YANG

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Search for more papers by this author

https://doi.org/10.1142/S0218625X09012937Cited by:3 (Source: Crossref)

Abstract

A manganese oxide contained coating was prepared on biodegradable AZ31B magnesium alloy to control the degradation of AZ31B and improve its biocompatibility. Morphology, composition, and corrosion resistance of the coating were studied. The SEM observations showed that the coating was approximately 4–6 μm in thickness with net-like microcracks. The XPS analysis indicated that the coating was mainly composed of MgO, Mg(OH)₂, MnO₂, Mn₂O₃, and Mn₃O₄. It was found that AZ31B with such coating showed better corrosion resistance in simulated blood plasma through electrochemical and immersion tests. The hemolytic assay indicated that the treated AZ31B had no hemolytic effect.

Keywords:

References

T. Xu and C. B. He, Guangdong Trace Elem. Sci. 6, 11 (2003). Web of Science, Google Scholar
E. Nilset al., Clin. Chim. Acta 294, 1 (2000). Crossref, Web of Science, Google Scholar
J. Zhang et al. , Magnesium Alloys and Their Application ( Chemical Industry Press , 2004 ) . Google Scholar
F. Z. Cui and Q. L. Feng , Biomaterials Science ( Tsinghus University Press , Beijing , 2004 ) . Google Scholar
P. Mark Staigeret al., Biomaterials 27, 1728 (2006). Crossref, Web of Science, Google Scholar
Y. J. Zhanget al., J. Mater. Prot. 4, 4 (2002). Web of Science, Google Scholar
W. Franket al., Biomaterials 7, 1013 (2006). Google Scholar
F. Witteet al., Biomaterials 17, 3557 (2006). Google Scholar
G. L. Song and S. Z. Song, Acta Phys. Chim. Sin. 10, 1222 (2006). Google Scholar
G. L. Song and S. Z. Song, Adv. Eng. Mater. 4, 298 (2007). Web of Science, Google Scholar
T. T. Yanet al., Mater. Rev. 1, 110 (2008). Google Scholar
http://articles.directorym.com/Manganese-a853030. html . Google Scholar
ISO 10993-4, Biological Evaluation of Medical Devices — Part 4: Selection of Tests for Interactions with Blood (2006) . Google Scholar
U. Hiroyuki, T. Matsufumi and K. Yo, Mater. 8, 1691 (2001). Google Scholar
ISO 7405, Dentistry — Preclinical Evaluation of Biocompatibility of Medical Devices Used in Dentistry — Test Methods for Dental Materials (1997) . Google Scholar
P. Haveet al., J. Cell Biol. 63, 1 (1974). Web of Science, Google Scholar
Z. H. Zhang and Y. Y. Zhu, J. Fudan Univ. 4, 40 (1985). Google Scholar