Regular ArticleNo Access

PREPARATION AND CHARACTERIZATION OF ORGANIC MODIFIED CALCIUM CARBONATE BY SODIUM STEARATE (OR SODIUM OLEATE) USING WET METHOD

School of Materials Science and Technology, Shenyang University of Chemical Technology, Shenyang 110142, Liaoning Province, China

Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, China

E-mail Address: liangyuaadd@126.com

Corresponding author.

Search for more papers by this author

SIJIA SUN

E-mail Address: sunsijia@cugb.edu.cn

Search for more papers by this author

HAO DING

E-mail Address: dinghao@cugb.edu.cn

E-mail Address: dinghao113@126.com

Search for more papers by this author

, and

XIFENG HOU

E-mail Address: houxifeng3204114@126.com

Search for more papers by this author

https://doi.org/10.1142/S0218625X1950224XCited by:9 (Source: Crossref)

Abstract

A method of modifying calcium carbonate particles was investigated by coating sodium stearate or sodium oleate on the surface of calcium carbonate by wet method. The results of FTIR, activation and dispersion index, dispersity in kerosene, surface wettability tests and zeta potential tests show that sodium stearate or sodium oleate has successfully coated on the surfaces of calcium carbonate. The main factors were researched and the optimal parameters were obtained for the best modification effect. Compared with common rubber, the modified calcium carbonate added rubber has larger breaking tensile strength (more than 21%) and larger elongation at break (more than 16%). This research provides a feasible way of modifying calcium carbonate for its use as filler in organic matrix, reduces the cost and has a potential application in large-scale production of modified calcium carbonate.

Keywords:

References

1. Y. Yang, Preparation of Modified Nano-CaCO3 and its Application in Lubricating Oil (Zhejiang University, 2016). Google Scholar
2. C. Yang, Preparation of Nano-CaCO3 and Size, Morphology Control (Donghua University, 2014). Google Scholar
3. X. Wu, Surface Modification of Ultrafine Ground Calcium Carbonate and its Applied Research on PVC Products (Anhui University of Science & Technology, 2006). Google Scholar
4. Y. Osaka, T. Tsujiguchi, A. Kodama and H. Y. Huang, J. Mater. Cycles Waste Manag. 22 (2020) 470. Crossref, Web of Science, Google Scholar
5. Y. Chen and X. Ji, Technol. Develop. Chem. Indus. 42 (2013) 31. Google Scholar
6. N. Osada, C. Otsuka, Y. Nishikawa and T. Kasuga, Mater. Lett. 264 (2020) 3. Crossref, Web of Science, Google Scholar
7. X. Zheng, L. Tan and Z. Li, Polyv. Chlor. 45 (2017) 26. Google Scholar
8. Q. Wang, The Modification of Ground Calcium Carbonate and its Application in Polypropylene (Huazhong University of Science and Technology, 2015). Google Scholar
9. Y. Huang, Study on Accelarating Aging and Application of CaCO3 Filling Polyethylene (Nanjing Forestry University, 2013). Google Scholar
10. G. Li, The Dispersion Method of CaCO3 in Liquid Silicone Rubber (Beijing University of Chemical Technology 2017). Google Scholar
11. R. Wan, Application of Regenerated Gum in the Tire Tread Compounds (Qingdao University of Science and Technology, 2018). Google Scholar
12. Y. Fan, Study on the Preparation and Properties of Calcium Carbonate Whisker/PVC/NBR Composites (Xi’an University of Science and Technology, 2016). Google Scholar
13. Y. Li, Study Characterization of ink Penetration into Coated Paper and Factors Affecting ink Penetration (South China University of Technology, 2011). Google Scholar
14. S. Zhang, Research on Modification of Nano-CaCO3 used in ink by Compound Modification Agent (Northeastern University, 2009). Google Scholar
15. Z. Yang, Preparation of Styrene-Acrylic Emulsion Modified by CaCO₃ Nanoparticles and its Application in Paper Coatings (Zhejiang Sci-Tech University, 2014). Google Scholar
16. V. Alvarez, N. S. J. Williams and M. Paulis, Prog. Org. Coat. 136 (2019) 7. Google Scholar
17. J. Huang, Study on Coating Process and Mechanism of Calcium Carbonate/Polymer Resin Blend Printing Material (Fujian Agriculture and Forestry University, 2012). Google Scholar
18. B. Zheng, Preparation of Starch-Coated Calcium Carbonate Filler and its Application in Manufacture of Copy Paper (Fujian Agriculture and Forestry University, 2016). Google Scholar
19. Z. Jiang, J. Wang, R. Ge and C. Wu, Polym. Bull. 75 (2017) 1. Web of Science, Google Scholar
20. V. Alvarez, N. S. J. Williams and M. Paulis, Prog. Org. Coat. 134 (2019) 281. Crossref, Web of Science, Google Scholar
21. O. A. Jimoh, K. S. Ariffin, H. Bin Hussin and A. E. Temitope, Carbonate. Evaporite. 33 (2018) 331. Crossref, Web of Science, Google Scholar
22. H. Jiang and D. P. Kamdem, Appl. Surf. Sci. 256 (2010) 4559. Crossref, Web of Science, ADS, Google Scholar
23. H. Zaman, P. Hun, R. Khan and K. Yoon, J Thermoplast Compos. Mater. 26 (2013) 1057. Crossref, Web of Science, Google Scholar
24. J. H. Kim, J. H. Ahn, J. S. Hong and K. H. Ahn, Korea-Aust. Rheol. J. 32 (2020) 29. Crossref, Web of Science, Google Scholar
25. X. Chen, K. Liu, H. Chen, Y. Zhao and L. Liu, J. Southern Yangtze Univ. (2002) 266. Google Scholar
26. D. Zhao, C. Wang, R. Zhuo and S. Cheng, Colloids Surf. B. 118 (2014) 111. Crossref, Web of Science, Google Scholar
27. M. Ucurum, O. Bayram, O. Toraman, H. Kilic and S. Yalcin, Physicochem. Probl. Miner. Process. 54 (2018) 688. Google Scholar
28. M. A. Osman and U. W. Suter, Chem. Mater. 14 (2002) 4408. Crossref, Web of Science, Google Scholar
29. Y. Sheng, B. Zhou, C. Wang and X. Zhao, Appl. Surf. Sci. 253 (2006) 1983. Crossref, Web of Science, ADS, Google Scholar
30. W. El Malti, D. Laurencin, G. Guerrero, M. E. Smith and P. H. Mutin, J. Mater. Chem. 22 (2011) 1212. Crossref, Google Scholar
31. H. Ding, S. Lu, Y. Deng and G. Du, Trans. Nonferrous Met. Soc. China 17 (2007) 1100. Crossref, Web of Science, Google Scholar
32. Z. F. Luo, J. F. Zhu, L. G. Tang, Y. M. Zhao, J. Guo, W. Zuo and S. L. Chen, Int. J. Miner. Process. 94 (2010) 166. Crossref, Google Scholar
33. Z. Wang, Practical Infrared Spectroscopy, 2nd edn. (Petroleum Industry Press, 1990). Google Scholar
34. G. Zhang, Mineralogy of Nonmetallic Minerals (Wuhan University of Technology Press, 1989). Google Scholar
35. L. Wen, Infrared Spectroscopy of Minerals (Chongqing University Press, 1989). Google Scholar
36. H. Ding, Multipurpose Util. Miner. Res. (1993) 45. Google Scholar
37. S. Li, H. Xu and J. Shen, Crystallography and Mineralogy (Geological Publishing House, 2008). Google Scholar
38. H. S. Hanna and P. Somasundaran, Flotation of Salt-Type Minerals Floatation (American Institute of Mining, Metallurgical and Petroleum Engineers Inc., New York, 1976). Google Scholar
39. D. Wang and Y. Hu, Floatation Solution Chemistry (Science and Technology of Hunan Press, 1988). Google Scholar