In this paper, by using the G2-structure on Im(O)≅R7 from the octonions O, the G2-binormal motion of curves γ(t,s) in R7 associated to the almost complex structure on S6 is studied. The motion is proved to be equivalent to Schrödinger flows from R1 to S6, and also to a nonlinear Schrödinger-type system (NLSS) in three unknown complex functions that generalizes the famous correspondence between the binormal motion of curves in R3 and the focusing nonlinear Schrödinger (NLS) equation. Some related geometric properties of the surface Σ in Im(O) swept by γ(t,s) are determined.