Part 1: Physics of NanostructuresNo Access

Thermodynamic Investigation of Polyhydroxylated Derivatives of Light Fullerenes

Institute of Chemistry, St Petersburg State University, Universitetskaya Emb. 13B, 199034 St Petersburg, Russia

and

Research Institute for Chemistry, Lobachevsky State University of Nizhny Novgorod, 603950 Nizhny Novgorod, Gagarin Ave. 23, Russia

E-mail Address: maxlelet@gmail.com

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https://doi.org/10.1142/S0219581X1940009XCited by:0 (Source: Crossref)

This article is part of the issue:

Special Issue — International Conference Nanomeeting 2019, 21st–24th May 2019; Editors: V. E. Borisenko (Minsk, Belarus), V. S. Gurin (Minsk, Belarus), C. H. Kam (Singapore, Singapore) and D. B. Migas (Minsk, Belarus)

Abstract

Isobaric heat capacities of C $_{60}$ (OH) $_{40}$ and C $_{70}$ (OH) $_{12}$ fullerenols were measured using adiabatic calorimetry in the temperature range of 0–320K along with standard thermodynamic functions: $S_{m}$ , [ $Φ_{m} (T) - Φ_{m} (0)$ ] and [ $H_{m} (T) - H_{m} (0)$ ]. Furthermore, the molar entropy of formation and the molar third law entropy of C $_{60}$ (OH) $_{40}$ and C $_{70}$ (OH) $_{12}$ in crystalline state at 298.15K were calculated.