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Recent developments in the coordination chemistry of porphyrin complexes containing non-metallic and semi-metallic elements

Penelope J. Brothers

Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand

Corresponding author, fax: +649 373 7422.

https://doi.org/10.1142/S1088424602000294Cited by:41 (Source: Crossref)

Abstract

Recent advances in the chemistry of main group porphyrin complexes are surveyed. New, unprecedented structural types for porphyrin complexes which have been revealed from the recent reports of boron and tellurium porphyrins are described. Advances in the preparation and reactivity of Group 14 (silicon and tin) and Group 15 porphyrin complexes are discussed. A systematic variation in the out-of-plane distortion (ruffling) of light element Group 14 and 15 porphyrin complexes has become apparent now that a significant number of structurally characterized examples are at hand.

Keywords:

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