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Recent developments in robust microporous porphyrin solids

Dennis W. Smithenry

School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Avenue, Urbana, IL 61801, USA

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and

Kenneth S. Suslick

School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Avenue, Urbana, IL 61801, USA

Corresponding author.

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https://doi.org/10.1142/S1088424604000179Cited by:16 (Source: Crossref)

Abstract

A review of the recent literature is presented which assesses the development of robust microporous porphyrin framework solids and their potential to perform selective sorption or heterogeneous shape- or size-selective catalysis. The review focuses only on those porphyrin solids whose porosity is robust, i.e. whose framework remains after the removal of solvates, as determined by thermal gravimetric analysis (TGA), X-ray powder diffraction (XRD), or gas adsorption studies. Eleven such robust porphyrin framework solids are presented.

Dedicated to Professor Hisanobu Ogoshi on the occasion of his 70^th birthday

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