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Synthesis of new carboran-based phthalocyanines and study of their activities in the photooxidation of citronellol

University of Bremen, Institute for Organic and Macromolecular Chemistry, Leobener Str. NW II, 28359 Bremen, Germany

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str. 28, Moscow 119991, Russia

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Dieter Wöhrle

University of Bremen, Institute for Organic and Macromolecular Chemistry, Leobener Str. NW II, 28359 Bremen, Germany

Corresponding author, fax: +49 421-2184935

SPP full member in good standing

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, and

Vladimir I. Bregadze

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str. 28, Moscow 119991, Russia

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https://doi.org/10.1142/S1088424605000344Cited by:31 (Source: Crossref)

Abstract

The synthesis and characterization of novel phthalocyanines containing o-carborane groups are described. These new tetrasubstituted phthalocyanines are of interest for the use in cancer therapy. The activities of the carboranyl substituted phthalocyanines were evaluated by the photooxidation of (S)-(−)-citronellol to give a high oxygen consumption comparable to the photosensitizers tetrasulfophthalocyanine zinc complexes.

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