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Novel one-pot regioselective route towards heteroleptic lanthanide (phthalocyaninato)(porphyrinato) triple-decker complexes

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences., Leninsky prosp. 31, 119991 Moscow, Russia

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Yulia G. Gorbunova

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences., Leninsky prosp. 31, 119991 Moscow, Russia

Corresponding author, fax: +7 (495) 952-25-66.

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, and

Aslan Yu. Tsivadze

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences., Leninsky prosp. 31, 119991 Moscow, Russia

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https://doi.org/10.1142/S1088424609000358Cited by:16 (Source: Crossref)

Abstract

A novel one-pot method for the regioselective preparation of early heteroleptic lanthanide (porphyrinato)(phthalocyaninato) complexes of double- and triple-decker structure [(Por)Ln(Pc) and (Por)Ln(Pc)Ln(Por), respectively] is developed. Sandwich-type complexes are synthesized for La, Ce and Pr following this procedure, with yields up to 30%. Tetrakis(15-crown-5)-phthalocyanine [(15C5)₄PcH₂] and tetrakis-meso-(4-methoxyphenyl)-porphyrin (An₄PH₂) are used as macrocyclic tetrapyrrolic ligands. The complexes are widely characterized with various physico-chemical methods (NMR and UV-vis spectroscopy, MALDI-TOF mass spectrometry). Quantum chemistry calculations for intermediates of the process are performed. The results of calculations explain the high regioselectivity of the triple-decker complex formation in the developed method.

Keywords:

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