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Synthesis of unusual phthalocyanines and naphthalocyanines

Michael Hanack

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

Corresponding author, tel: +49 7071-2972432, fax: +49 7071-295268.

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Zafar Iqbal

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

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Alexey Lyubimtsev

Ivanovo State University of Chemistry and Technology, Organic Chemistry Department, F. Engels Str. 7, 153460 Ivanovo, Russia

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Ibrahim Özcesmeci

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

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Mukaddes Özcesmeci

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

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, and

Thomas Ziegler

Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

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https://doi.org/10.1142/S1088424609000395Cited by:13 (Source: Crossref)

Abstract

This paper is a summary of the lecture Michael Hanack gave at the 5th ICPP meeting in Moscow. A new method for the preparation of phthalonitriles is reported which makes the syntheses of substituted phthalocyanines much easier. Then the generation of highly reactive dehydrophthalocyanines using different methods is described. The reaction of these intermediates with dienophiles and various solvents is also discussed. In the last section, the syntheses of tetra- and octa- Zn phthalocyanine and -naphthalocyanine carbohydrate conjugates, which will be used for photosensitizers in PDT, is reported.

Keywords:

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