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Directed synthesis of bi- and polynuclear clamshell-type phthalocyanines and their physico-chemical investigations

Institute of Physiologically Active Compounds of Russian Academy of Science, 142432 Chernogolovka, Moscow Region, Russian Federation

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Victor E. Pushkarev

Institute of Physiologically Active Compounds of Russian Academy of Science, 142432 Chernogolovka, Moscow Region, Russian Federation

Department of Chemistry, M.V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

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Evgeny V. Shulishov

N.D. Zelinsky Institute of Organic Chemistry (ZIOC RAS), 119991 Moscow, Russian Federation

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, and

Larisa G. Tomilova

Institute of Physiologically Active Compounds of Russian Academy of Science, 142432 Chernogolovka, Moscow Region, Russian Federation

Department of Chemistry, M.V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

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https://doi.org/10.1142/S108842461250037XCited by:17 (Source: Crossref)

Abstract

Novel bi-, tri- and tetranuclear butyl- and tert-butyl-substituted clamshell-type phthalocyanines were synthesized starting from 2-hydroxyphthalocyanines with quantitative yields. The structures of the obtained compounds were characterized by a complex of NMR spectroscopy and mass spectrometry techniques. Applying electronic absorption spectroscopy (UV-vis) and density functional theory (DFT) showed the complicated conformation equilibria for the spacer-bonded macrocyclic compounds and led us to estimate their behavior dependent on the number and relative orientation of macrocycles.

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