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The first push-pull μ-nitrido iron phthalocyanine dimer

Ümit İşci

Gebze Institute of Technology, Department of Chemistry, P.O. Box 141, Gebze 41400, Turkey

Corresponding author, fax: +90 262-605-3109.

https://doi.org/10.1142/S1088424613500880Cited by:8 (Source: Crossref)

Abstract

The first push-pull μ-nitrido diiron phthalocyanine complex was prepared and characterized. The EPR spectrum confirms the Fe^+3.5–N–Fe^+3.5 formalism. The stability of this dimer in oxidant media (up to 1000 equivalent of H₂O₂) was studied by UV-vis spectroscopy. The push-pull μ-nitrido diiron phthalocyanine exhibited excellent stability because of the delocalization of an unpaired electron.

Dedicated to Professor Vefa Ahsen on the occasion of his 60th birthday

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