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Macrocyclic dipyrrin dimer bridged by ethylene and dioxyphenylene linkers

Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan

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Satoru Hiroto

Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan

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Hiroshi Shinokubo

Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan

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https://doi.org/10.1142/S108842461450093XCited by:2 (Source: Crossref)

Abstract

A tetrapyrrolic macrocycle containing ethenylene and dioxyphenylene bridges was obtained through the reaction of a dipyrrin-DDQ adduct with triethylamine. The structure of the macrocycle was elucidated by X-ray diffraction analysis. The macrocycle exhibited solvent-dependent absorption spectra due to intramolecular charge transfer interactions.

Dedicated to Professor Shunichi Fukuzumi on the occasion of his retirement.

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