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Synthesis of meta-methoxyphenyl substituted tetraazaporphyrin and corrolazine phosphorus(V) complexes

Taniyuki Furuyama

Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

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Yusuke Sugiya

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

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Takuya Yoshida

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

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, and

Nagao Kobayashi

Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

Faculty of Textile Science and Technology, Shinshu University, Tokida, Ueda 386-8567, Japan

E-mail Address: nagaok@shinshu-u.ac.jp

Corresponding author: tel/fax:+81 268-21-5499.

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https://doi.org/10.1142/S1088424616500619Cited by:4 (Source: Crossref)

Abstract

Octa-(meta-methoxyphenyl) substituted tetraazaporphyrin (TAP, 1) and corrolazine (Cor, 4) phosphorus(V) complexes have been synthesized and characterized. 1 has a blue-shifted, small charge transfer (CT) band while para-methoxyphenyl substituted PTAP 2 has a red-shifted, intense CT band. The difference could be interpreted as an inductive effect of the meta-methoxy groups. The position and intensity of the absorption bands of 1 are well matched to the trend of para-substituted PTAPs. The synthesis of PCor from free-base TAP was also investigated. The PCor was not generated directly but from a PTAP intermediate

Dedicated to Professor Tomás Torres on the occasion of his 65th birthday

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