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Electroconductive films based on amino-substituted tetraphenylporphyrins and their metal copper complexes

Mariya V. Tesakova

G.A. Krestov Institute of Solution Chemistry of RAS, Akademicheskaya St., 1, Ivanovo 153045, Russia

E-mail Address: mvt@isc-ras.ru

Corresponding author, tel: +7 (4932)-336-264 (2-27)

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Aleksandr S. Semeikin

Ivanovo State University of Chemistry and Technology, Sheremetevsky Avenue 7, Ivanovo 153000, Russia

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, and

Vladimir I. Parfenyuk

G.A. Krestov Institute of Solution Chemistry of RAS, Akademicheskaya St., 1, Ivanovo 153045, Russia

SPP full member in good standing.

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https://doi.org/10.1142/S1088424616500930Cited by:23 (Source: Crossref)

Abstract

Amino-substituted tetraphenylporphyrins (5,10,15,20-tetrakis(4′-aminophenyl)porphyrin, 5-(4′-aminophenyl)–10,15,20-triphenylporphyrin) and their copper complexes in dichloromethane and ethanol were electropolymerized by the cyclic voltammetry method and their electrochemical properties were studied. The polyporphyrin films obtained by electro-oxidation transmit electricity and possess semiconductor properties of different types. The poly-5,10,15,20-tetrakis(4′-aminophenyl)porphyrin films obtained from different solvents are similar to each other in chemical composition but different in morphology. The polyporphyrin film surface morphology was studied by AFM microscopy.

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References

1. Ferreira LMC, Grasseschi D, Santos MSF, Martins PR, Gutz IGR, Ferreira AMC, Araki K, Toma HE and Angnes L. Langmuir. 2015; 31: 4351–4360. Crossref, Web of Science, Google Scholar
2. Wróbel D. C. R. Chim. 2003; 6: 417–429. Crossref, Web of Science, Google Scholar
3. Basu J and Rohatgi-Muherjee KK. Sol. Energy Mater. 1991; 21: 317–325. Crossref, Web of Science, Google Scholar
4. Licht S, Myung N and Sun Y. Anal. Chem. 1996; 68: 954–959. Crossref, Web of Science, Google Scholar
5. Law K-Y. Chem. Rev. 1993; 93: 449–486. Crossref, Web of Science, Google Scholar
6. Jasinski R. Nature 1964; 201: 1212–1213. Crossref, Web of Science, Google Scholar
7. Buttry DA and Anson FC. J. Am. Chem. Soc. 1984; 106: 59–64. Crossref, Web of Science, Google Scholar
8. Pontie M, Lecture H and Bedioui F. Sens. Actuators B. 1999; 56: 1–5. Crossref, Web of Science, Google Scholar
9. Bedioui F, Trevin S, Devynck J, Lantoine F, Brunet A and Devynck MA. Biosens. Bioelectron. 1997; 12: 205–212. Crossref, Web of Science, Google Scholar
10. Ureta-Zañartu MS, Berrıós C, Pavez J, Zagal J, Gutiérrez C and Marco JF. J. Electroanal. Chem. 2003; 553: 147–156. Crossref, Web of Science, Google Scholar
11. Kimura M, Yamaguchi Y, Koyama T, Hanabusa K and Shirai H. J. Porphyrins Phthalocyanines 1997; 1: 309–313. Link, Web of Science, Google Scholar
12. Bettelheim A, White BA, Raybuck SA and Murray RW. Inorg. Chem. 1987; 26: 1009–1017. Crossref, Web of Science, Google Scholar
13. Durantini J, Morales GM, Santo M, Funes M, Durantini EN, Fungo F, Dittrich Th, Otero L and Gervaldo M. Org. Electron. 2012; 13: 604–614. Crossref, Web of Science, Google Scholar
14. Jin G, Zhang Y and Cheng W. Sens. Actuators B. 2005; 107: 528–534. Crossref, Web of Science, Google Scholar
15. Kadish KM and Morrison MM. J. Am. Chem. Soc. 1976; 98: 3326–3328. Crossref, Web of Science, Google Scholar
16. Kadish KM, Lin M, Van Caemelbecke E, De Stefano G, Medforth CJ, Nurco DJ, Nelson NY, Krattinger B, Muzzi CM, Jaquinod L, Xu Y, Shyr DC, Smith KM and Shelnutt JA. Inorg. Chem. 2002; 41: 6673–6687. Crossref, Web of Science, Google Scholar
17. Fujii H. J. Am. Chem. Soc. 1993; 115: 4641–4648. Crossref, Web of Science, Google Scholar
18. Durantini J, Otero L, Funes M, Durantini EN, Fungo F and Gervaldo M. Electrochim. Acta. 2011; 56: 4126–4134. Crossref, Web of Science, Google Scholar
19. Walter MG and Wamser CC. J. Phys. Chem. C. 2010; 114: 7563–7574. Crossref, Web of Science, Google Scholar
20. Armijo F, Ferraudi G, Isaacs F, Aguirre MJ and Costamagna J. Inorg. Chim. Acta. 2006; 359: 2281–2284. Crossref, Web of Science, Google Scholar
21. Armijo F, Goya C, Reina M, Canales J, Arevalo C and Aguirre J. J. Mol. Catal. A: Chem. 2007; 268: 148–154. Crossref, Web of Science, Google Scholar
22. Semeikin AS, Koifman OI and Berezin BD. Chem. Heterocycl. Compd. 1983; 18: 1046–1047. Crossref, Google Scholar
23. Salnikova MA, Lubimova TV, Glazunov AV, Syrbu SA and Semeikin AS. Macroheterocycles 2014; 7: 249–255. Crossref, Web of Science, Google Scholar
24. Tesakova MV, Popov IA and Parfenyuk VI. Russ. J. Electrochem. 2014; 50: 517–522. Crossref, Web of Science, Google Scholar
25. Tesakova MV, Sheinin VB and Parfenyuk VI. Russ. J. Phys. Chem. A. 2014; 88: 325–330. Crossref, Web of Science, Google Scholar
26. Chen S-M and Chen Y.L. J. Electroanal. Chem. 2004; 573: 277–287. Crossref, Web of Science, Google Scholar
27. Armijo F, Goya MC, Gimeno Y, Arev́alo MC, Aguirre MJ and Creus AH. Electrochem. Commun. 2006; 8: 779–784. Crossref, Web of Science, Google Scholar
28. Vernitskaya TV. Russ. Chem.Rev. 1997; 66: 443–457. Crossref, Google Scholar
29. Tesakova MV and Parfenyuk VI. J. Adv. Mater. 2015; 10: 12–21. Google Scholar
30. Zujovic ZD, Zhang L, Bowmaker GA, Kilmartin PA and Travas-Sejdic J. Macromolecules 2008; 41: 3125–3135. Crossref, Web of Science, Google Scholar
31. Trchova M, Sedenkova I, Konyushenko E, Stejskal J, Holler P and Ciric-Marjanovic G. J. Phys. Chem. B. 2006; 110: 9461–9468. Crossref, Web of Science, Google Scholar
32. Wheaton G, Stoel L, Stevens N and Frank C. Appl. Spectrosc. 1970; 24: 339–343. Crossref, Web of Science, Google Scholar
33. Nekrasov AA and Vannikov AV. Russ. J. Electrochem. 2011; 47: 1–14. Crossref, Web of Science, Google Scholar
34. Brédas J. In Handbook of Conducting Polymers, Vol. 2, Skotheim TA. (Ed.) Marcel Dekker, Inc.: New York, 1986; pp. 859–914. Google Scholar
35. Gutsev GL, Boldyrev AI and Ovchinnikov AA. Dokl. Phys. Chem. 1987; 292: 391–394. Google Scholar