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Ruffling and doming: Structural and redox studies on meso-aryl and $β$ -alkyl chromyl(V)corroles

Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

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Christian Kleeberg

Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

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Dominik Körner

Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

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Anne Thüsing

Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

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Richard Wicht

Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

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Marc-Kevin Zaretzke

Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

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, and

Martin Bröring

Institute of Inorganic and Analytical Chemistry, Technical University Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

E-mail Address: m.broering@tu-bs.de

Corresponding author, IAAC, TU Braunschweig, Hagenring 30, 38106 Braunschweig, Germany. Phone: int (+)531 3915302.

SPP full member in good standing.

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https://doi.org/10.1142/S1088424619500792Cited by:4 (Source: Crossref)

Abstract

Chromyl(V) complexes of eleven different meso-aryl- and $β$ -alkylcorrole ligands have been prepared and characterized by analytical, spectroscopical, electrochemical and structural means. All seven new complexes show the expected optical spectra of chromyl(V) corroles with the Soret band situated slightly above (meso-arylcorroles) or below ( $β$ -alkylcorrole) 400 nm, and with an isotropic room temperature EPR signal for the $d^{1}$ ion Cr(V) at about $g_{iso} = 1.985$ . Cyclic voltammetry evidences two or three quasi-reversible one-electron redox steps, which are characterized as two ligand-centered processes and one metal-centered process based on spectroelectrochemical measurements and a Hammett analysis. Chemical reduction to a chromyl(IV) corrolate was successfully performed using NaHg and NEt₃. Citric acid, however, produces a different reduction product, for which an isocorrole structure is proposed. Six chromyl(V) corroles could be analysed by seven single crystal diffraction analyses. The obtained molecular data prove the presence of remarkably similar CrN₄O coordination units independent of the corrole substitution pattern, and of macrocyclic conformations which can be understood as comprised mainly of a doming mode, a more or less pronounced saddling mode, and one out of two different and dominating ruffling modes.

Dedicated to Professor Atsuhiro Osuka in celebration of his 65th birthday.

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