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A temperature switchable pyridyl-zinc(II) side arm porphyrin with functionality for surface immobilisation

Flinders Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, Adelaide, Australia

Current address: Research School of Chemistry, Australian National University, Australian Capital Territory, Australia

ORCID 0000-0003-3069-5352.

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Martin R. Johnston

Flinders Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, Adelaide, Australia

E-mail Address: martin.johnston@flinders.edu.au

Corresponding author.

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https://doi.org/10.1142/S1088424621500759Cited by:0 (Source: Crossref)

Abstract

A pyridyl side arm porphyrin incorporating C $_{10}$ $_{10}$ alkyl chains at the periphery of the porphyrin suitable for surface immobilisation on HOPG has been synthesised and tested for two state switching in solution. Temperature switching, involving reversible complexation of a covalently appended pyridyl side arm to the Zn(II) porphyrin, was comprehensively characterised by using variable temperature ¹H NMR (-30 to +100 $^{\circ}$ $^{\circ}$ C) and UV-vis (10 to 90 $^{\circ}$ $^{\circ}$ C) in toluene. Molecular modelling assisted in understanding strain within the complex.

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