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Synthesis, redox properties, and catalytic hydrogen gas generation of porphycene cobalt complexes

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

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Taro Koide

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

E-mail Address: koide@mail.cstm.kyushu-u.ac.jp

Corresponding author, phone: +81-92-802-2831, fax: +81-92-802-2831.

SPP full member in good standing.

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Yoshihito Shiota

Institute for Materials Chemistry and Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka 819-0395, Japan

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Yoshio Yano

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

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Ning Xu

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

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Toshikazu Ono

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

Center for Molecular Systems (CMS), Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

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Hisashi Shimakoshi

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

SPP full member in good standing.

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Kazunari Yoshizawa

Institute for Materials Chemistry and Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka 819-0395, Japan

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, and

Yoshio Hisaeda

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

Center for Molecular Systems (CMS), Kyushu University, Moto-oka 744, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

E-mail Address: yhisatcm@mail.cstm.kyushu-u.ac.jp

Corresponding author, phone: +81-92-802-2103, fax: +81-92-802-2119.

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https://doi.org/10.1142/S108842462250016XCited by:1 (Source: Crossref)

Abstract

A new meso-tetrakis(3,5-di-tert-butylphenyl) substituted porphycene and its cobalt complex were synthesized and characterized. Several meso-tetraarylporphycene cobalt complexes having different substituents showed catalytic activity for the hydrogen gas evolution reaction (HER) in the presence of trifluoroacetic acid (TFA) under electrochemical reductive conditions. The electrochemical potential of the HER was -1.50V vs. Ag/AgCl in THF. The active species of this reaction were determined to be the ligand reduced species of Co(II) porphycenes. The catalytic efficiencies of the cobalt complexes of meso-aryl substituted porphycenes and meso-tetraphenylporphyrin were compared and meso-tetraphenyl porphycene cobalt complex exhibited the best current efficiency of 72%. Based on these experimental results and theoretical calculations, we proposed a possible HER mechanism of this system.

Keywords:

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