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Catalytic Hydrogenation of Alkali Lignin Into Bio-Oil via Nano-Lamellar MoSe₂-Based Composite Catalysts

Advanced Catalysis and Green Manufacturing, Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China

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Jia Zhou

Advanced Catalysis and Green Manufacturing, Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China

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Yongwei Yu

Advanced Catalysis and Green Manufacturing, Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China

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Jiangquan Ma

http://orcid.org/0000-0001-7713-7716

Advanced Catalysis and Green Manufacturing, Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China

E-mail Address: majiangquan@126.com

Corresponding author.

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Xueni Sun

Advanced Catalysis and Green Manufacturing, Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China

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, and

Lanmei Hu

Advanced Catalysis and Green Manufacturing, Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China

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https://doi.org/10.1142/S1793292017501211Cited by:6 (Source: Crossref)

Abstract

In this research, a series of catalysts based on MoSe₂ were synthesized by the hydrothermal method and used for the catalytic hydrogenation of alkali lignin for the first time. For 4wt.% NiSe₂/MoSe₂ catalyst, at 290 $^{\circ}$ C, under 2MPa H₂ pressure for 1.5h, the conversion of alkali lignin and the yield of bio-oil reached 96.47% and 93.68%, respectively. In addition, the composition of the product (bio-oil) was analyzed via Fourier transform infrared (FTIR) spectrometry, gas chromatography-mass spectrometry (GC-MS) spectra, and proton nuclear magnetic resonance (¹HNMR) spectra. Finally, our study demonstrated that those MoSe₂-based composite catalysts can effectively degrade the biomass into bio-oil containing valuable chemical products.

Keywords:

References

1. C. O. Tuck, E. Perez, I. T. Horvath, R. A. Sheldon and M. Poliakoff, Science 337, 695 (2012). Crossref, Web of Science, Google Scholar
2. P. J. Deuss and K. Barta, Coordin. Chem. Rev. 306, 510 (2016). Crossref, Web of Science, Google Scholar
3. P. Posoknistakul, T. Akiyama, T. Yokoyama and Y. Matsumoto, J. Wood Chem. Technol. 36, 288 (2016). Crossref, Web of Science, Google Scholar
4. A. Azarpira, J. Ralph and F. C. Lu, Bioenerg. Res. 7, 78 (2014). Crossref, Web of Science, Google Scholar
5. H. Werhan, J. M. Mir, T. Voitl and P. R. von Rohr, Holzforschung 65, 703 (2011). Crossref, Web of Science, Google Scholar
6. R. J. A. Gosselink, W. Teunissen, J. E. G. van Dam, E. de Jong, G. Gellerstedt, E. L. Scott and J. P. M. Sanders, Bioresource Technol. 106, 173 (2012). Crossref, Web of Science, Google Scholar
7. O. I. Senol, E. M. Ryymin, T. R. Viljava and A. O. I. Krause, J. Mol. Catal. A-Chem. 277, 107 (2007). Crossref, Google Scholar
8. A. L. Jongerius, R. Jastrzebski, P. C. A. Bruijnincx and B. M. Weckhuysen, J. Catal. 285, 315 (2012). Crossref, Web of Science, Google Scholar
9. P. de Wild, R. Van der Laan, A. Kloekhorst and E. Heeres, Environ. Prog. Sustain. 28, 461 (2009). Crossref, Web of Science, Google Scholar
10. M. Grilc, B. Likozar and J. Levec, ChemCatChem 8, 180 (2016). Crossref, Web of Science, Google Scholar
11. M. Grilc, B. Likozar and J. Levec, Catal. Today 256, 302 (2015). Crossref, Web of Science, Google Scholar
12. C. Alvarez-Vasco, R. Ma, M. Quintero, M. Guo, S. Geleynse, K. K. Ramasamy, M. Wolcott and X. Zhang, Green Chem. 18, 5133 (2016). Crossref, Web of Science, Google Scholar
13. G. Guerriero, J.-F. Hausman, J. Strauss, H. Ertan and K. S. Siddiqui, Eng. Life Sci. 16, 1 (2016). Crossref, Web of Science, Google Scholar
14. K. Kang, R. Azargohar, A. K. Dalai and H. Wang, Energ. Convers. Manage. 117, 528 (2016). Crossref, Web of Science, Google Scholar
15. M. Grilc, G. Veryasov, B. Likozar, A. Jesih and J. Levec, Appl. Catal. B-Environ. 163, 467 (2015). Crossref, Web of Science, Google Scholar
16. K. Yan, Y. Liu, Y. Lu, J. Chai and L. Sun, Catal. Sci. Technol. 7, 1622 (2017). Crossref, Web of Science, Google Scholar
17. S. Sahoo and C. S. Rout, Electrochim. Acta 220, 57 (2016). Crossref, Web of Science, Google Scholar
18. K. Zhou, X. Qian, R. Gao and F. Mei, J. Colloid Interf. Sci. 504, 158 (2017). Crossref, Web of Science, Google Scholar
19. V. V. Brazhkin, L. N. Dzhavadov and F. S. El’kin, Jetp Lett+. 104, 99 (2016). Crossref, Web of Science, Google Scholar
20. P. Luo, H. J. Zhang, L. Liu, Y. Zhang, J. Deng, C. H. Xu, N. Hu and Y. Wang, Acs Appl. Mater. Inter. 9, 2500 (2017). Crossref, Web of Science, Google Scholar
21. T. Jantzen, K. Hack, E. Yazhenskikh and M. Muller, Calphad 56, 286 (2017). Crossref, Google Scholar
22. J. Li, G. Q. Ding, D. Qin, K. Yao and G. Y. Gao, J. Alloy. Compd. 701, 754 (2017). Crossref, Web of Science, Google Scholar
23. J. M. P. Almeida, C. Lu, C. R. Mendonca and C. B. Arnold, Opt. Mater. Express 5, 1815 (2015). Crossref, Web of Science, Google Scholar
24. Q. Wang, L. X. Sun, B. Zhang, C. Q. Chen, X. C. Shen and W. Lu, Opt. Express 24, 7151 (2016). Crossref, Web of Science, Google Scholar
25. N. Singh, J. Hiller, H. Metiu and E. McFarland, Electrochim. Acta 145, 224 (2014). Crossref, Web of Science, Google Scholar
26. T. Yanase, S. Watanabe, M. T. Weng, M. Wakeshima, Y. Hinatsu, T. Nagahama and T. Shimada, Cryst. Growth Des. 16, 4467 (2016). Crossref, Web of Science, Google Scholar
27. M. Ghorbani-Asl, A. Kuc, P. Miro and T. Heine, Adv. Mater. 28, 853 (2016). Crossref, Web of Science, Google Scholar
28. N. X. Li, L. F. Wei, R. Bibi, L. Y. Chen, J. H. Liu, L. Zhang, Y. Q. Zheng and J. C. Zhou, Fuel 185, 532 (2016). Crossref, Web of Science, Google Scholar
29. T. Kubota, N. Miyamoto, M. Yoshioka and Y. Okamoto, Appl. Catal. A-Gen. 480, 10 (2014). Crossref, Web of Science, Google Scholar
30. I. A. Sizova, A. B. Kulikov, M. I. Onishchenko, S. I. Serdyukov and A. L. Maksimov, Petrol. Chem+. 56, 44 (2016). Crossref, Web of Science, Google Scholar
31. Y. L. Yap, X. W. Zhang, A. Andonov and R. T. He, Comput. Biol. Chem. 29, 212 (2005). Crossref, Web of Science, Google Scholar
32. Q. W. Tian, N. X. Li, J. H. Liu, M. Wang, J. Q. Deng, J. C. Zhou and Q. H. Ma, Energy Fuels 29, 255 (2015). Crossref, Web of Science, Google Scholar
33. H. Tang, H. Huang, X. S. Wang, K. Q. Wu, G. G. Tang and C. S. Li, Appl. Surf. Sci. 379, 296 (2016). Crossref, Web of Science, Google Scholar
34. P. P. Hankare, A. A. Patil, P. A. Chate, K. M. Garadkar, D. J. Sathe, A. H. Manikshete and I. S. Mulla, J. Cryst. Growth 311, 15 (2008). Crossref, Web of Science, Google Scholar
35. W. Narvaez, C. Priest, Q. Tang and D. E. Jiang, Mol. Simulat. 43, 379 (2017). Crossref, Web of Science, Google Scholar
36. M. Daage and R. R. Chianelli, J. Catal. 149, 414 (1994). Crossref, Web of Science, Google Scholar
37. V. M. Kogan and P. A. Nikulshin, Catal. Today 149, 224 (2010). Crossref, Web of Science, Google Scholar
38. H. Topsøe, B. S. Clausen, R. Candia, C. Wivel and S. Mørup, J. Catal. 68, 433 (1981). Crossref, Web of Science, Google Scholar
39. H. Topsøe, B. S. Clausen, N. Y. Topsøe, E. Pedersen, W. Niemann, A. Müller and B. Lengeler, J. Chem. Soc. Faraday. Trans. 83, 2157 (1987). Crossref, Google Scholar
40. N. Mahmood, Z. S. Yuan, J. Schmidt and C. B. Xu, Bioresource Technol. 139, 13 (2013). Crossref, Web of Science, Google Scholar
41. P. T. Patil, U. Armbruster, M. Richter and A. Martin, Energy Fuels 25, 4713 (2011) Crossref, Web of Science, Google Scholar