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Intercalation of Europium Inclusion Complex of $β$ -Cyclodextrin into Layered Double Hydroxides Through Layer-By-Layer Assembly and Its Luminescent Properties

Wenjun Zhang

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

E-mail Address: wjzhang@hebut.edu.cn

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Yi Chen

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Yanlin Li

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Sumin Guan

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Yan Chen

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Qian-Qian Yang

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Lu Liu

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Qing-Chen Xue

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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, and

Yu-Cui Guang

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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https://doi.org/10.1142/S1793292017501260Cited by:3 (Source: Crossref)

Abstract

In this work, organic–inorganic hybrid ultrathin transparent films (UTFs), produced by layer-by-layer (LBL) assembly of the europium inclusion complex of $β$ -cyclodextrin ( $β$ -CD) and Mg–Al-layered double hydroxide (MgAl–NO₃–LDHs) nanosheets, are reported. UV-visible (UV-Vis) absorption and fluorescence spectroscopy show orderly growth of the europium inclusion complex of $β$ -CD/layered double hydroxide (EICC/LDH) films with an increasing number of deposition cycles. X-ray diffraction and scanning electron microscopy measurements indicate that the films feature periodic layered structures with uniform surface morphology. Moreover, when EICC is assembled with inorganic rigid LDH nanosheets, the lifetimes are prolonged due to the isolation effect, and the UTFs are transparent with high brightness, which indicate that these films could serve as new optical materials.

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