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Waste Utilization Method for $δ$ -MnO₂ Anode Composited with MWCNT and Graphene by Embedding on Conductive Paper for Lithium-Ion Battery

Boya Zhang

College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, P. R. China

E-mail Address: 815252323@qq.com

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and

Jiaqi Wan

School of Materials Science and Engineering, Qingdao University of Science & Technology, Qingdao 266042, P. R. China

E-mail Address: wjiaq@qust.edu.cn

Corresponding author.

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https://doi.org/10.1142/S1793292019500516Cited by:3 (Source: Crossref)

Abstract

Lithium-ion batteries have received considerable attention as energy storage tool for modern-life equipments. However, drawbacks like low electric conductivity and volume expansion are the obstacles that hinder its application. To solve these problems, we developed a facile method using waste eggshell as hard template to reduce its particle size and change its morphology by simple hydrothermal process. Then, by utilizing waste paper, conductive paper (CP) current collector with graphene and multiwalled carbon nanotube implanted was prepared and combined with MnO₂ anode material. The composite anode shows extraordinary electrochemical performances like much smaller impedance, high reversible capacity of 1767/1762mAh/g even after 200 cycles at 100mA/g, superior rate performance, etc. Compared with anode using metal current collectors, this composite anode will reduce weight and can be generalized to other high energy storage applications. Our environment-friendly method has far-reaching referential significance to other active materials and battery systems.

Keywords:

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