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Synthesis of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ Nanorods by a Facile Self-Template Method and their Electrochemical Performances

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

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Xinlu Wang

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

E-mail Address: xinluwang@163.com

Corresponding authors.

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Qingnan Feng

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

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Chenglong Shao

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

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Guixia Liu

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

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Wensheng Yu

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

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Xiangting Dong

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

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, and

Jinxian Wang

https://orcid.org/0000-0002-9989-5603

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China

E-mail Address: wjx87@sina.com

Corresponding authors.

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https://doi.org/10.1142/S1793292022500503Cited by:0 (Source: Crossref)

Abstract

Lithium-rich manganese-based oxides have become one of the widely studied cathode materials for lithium-ion batteries due to their high-energy density, relatively low price and environmental friendliness. Herein, we propose a simple self-template route to prepare ${Li}_{1.2}$ ${Mn}_{0.54}$ ${Ni}_{0.13}$ ${Co}_{0.13}$ O₂ nanorods using rod-like Mn₂O₃ as templates. Besides, the effect of calcination temperature on the morphology and electrochemical properties of the electrode materials was investigated. ${Li}_{1.2}$ ${Mn}_{0.54}$ ${Ni}_{0.13}$ ${Co}_{0.13}$ O₂ nanorods as the cathode exhibit initial capacity of 251.4 mAh g^t1 at 0.1 C and capacity retention rate of 67.9% after 200 cycles, which can be attributed to the enhanced layered structural stability, lower charge transfer resistance and shorter lithium-ion transport pathway.

Keywords:

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