Large strain and pyroelectric properties of Pb(Mg1/3Nb2/3)O3–PbTiO3 ceramics prepared by partial oxalate route
Abstract
Partial oxalate route is an efficient method to synthesize complex perovskite ferroelectric ceramics, in which the synthesized (1 - x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMN–PT) ceramics exhibit rather pure perovskite structure, densified microstructure morphology, and excellent dielectric and piezoelectric properties. The PMN–PT ceramics synthesized by the partial oxalate route exhibit rather symmetric strain–electric (S–E) field hysteresis loops, where the strain is large and far less than saturated at 2 kV/mm. The PMN–PT ceramics exhibit excellent pyroelectric properties, in which the values of the pyroelectric coefficient and the calculated pyroelectric figures of merit maintain almost stable over the frequency range of 100 Hz–2000 Hz, and vary differently depending on composition with the increase of temperature. Such investigations reveal that high-performance piezoelectric and pyroelectric devices can be prepared by the partial oxalate route in low production cost.
