No Access

Synthesis and Properties of Tetrakis(trimethylsilyl)-phthalocyaninatoruthenium(II)

Institut für Organische Chemie, Lehrstuhl für Organische Chemie II der Universitat Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany

Search for more papers by this author

and

MICHAEL HANACK

Institut für Organische Chemie, Lehrstuhl für Organische Chemie II der Universitat Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany

Corresponding author: Institut für Organische Chemie, Lehrstuhl für Organische Chemie II der Universitat Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany.

Search for more papers by this author

https://doi.org/10.1002/(SICI)1099-1409(199903)3:3<224::AID-JPP126>3.0.CO;2-DCited by:13 (Source: Crossref)

Abstract

Tetrakis(trimethysilyl)phthalocyaninatoruthenium(II) (5) has been synthesized via the biaxially coordinated ((CH₃)₃Si)₄PcRu(3-Clpy)₂ (2) complex by thermal decomposition of the axial ligands of 2. ((CH₃)₃Si)₄PcRu (5) was characterized by NMR, IR and UV-vis spectroscopy and elemental analysis. The trisubstituted ((CH₃)₃Si)₃PcRu(3-Clpy)₂ (3) and disubstituted ((CH₃)₃Si)₂PcRu(3-Clpy)₂ (4) complexes, formed as side products during the thermolysis of 2, could be isolated and characterized.

Keywords:

Most comprehensive & up-to-date research on PORPHYRINS
Handbook of Porphyrin Science now available in 46 volumes

References

W. Kobel and M. Hanack, Inorg. Chem. 25, 103 (1986), DOI: 10.1021/ic00221a027. Crossref, Web of Science, Google Scholar
R. Polley and M. Hanack, Synthesis 295 (1997), DOI: 10.1055/s-1997-1174. Google Scholar
M. Hanacket al., Synthesis 211 (1992), DOI: 10.1055/s-1992-34149. Google Scholar
M. Hanack, S. Knecht and R. Polley, Chem. Ber. 128, 929 (1995), DOI: 10.1002/cber.19951280913. Crossref, Google Scholar
M. Hanack and R. Polley, Inorg. Chem. 33, 3201 (1994), DOI: 10.1021/ic00092a034. Crossref, Web of Science, Google Scholar
J. Pohmer, M. Hanack and J. O. Barcina, J. Mater. Chem. 957 (1996), DOI: 10.1039/jm9960600957. Google Scholar
T. Nyokong, Polyhedron 12, 375 (1993), DOI: 10.1016/S0277-5387(00)81741-6. Crossref, Web of Science, Google Scholar
M. Hanack and M. Lang, Adv. Mater. 6, 819 (1994), DOI: 10.1002/adma.19940061103. Crossref, Web of Science, Google Scholar
H. Schulzet al., Struct. Bonding (Berlin) 74, 41 (1990). Crossref, Web of Science, Google Scholar
M. Hanack and P. Vermehren, Synth. Met. 32, 257 (1989), DOI: 10.1016/0379-6779(89)90849-7. Crossref, Web of Science, Google Scholar
W. Eberhardt, PhD Thesis, Universität Tübingen (1998) . Google Scholar
H. Hopf and P. Gallegra, Helv. Chim. Acta 51, 253 (1958). Crossref, Web of Science, Google Scholar
M. Hanack, G. Schmid and M. Sommerauer, Angew. Chem. 105, 1540 (1993); Angew. Chem. Int. Ed. Engl. 32, 1422 (1993) . Google Scholar
M. Sommerauer, C. Rager and M. Hanack, J. Am. Chem. Soc. 42, 10085 (1996). Google Scholar
G. Schmidet al., Phthalocyanines, Properties and Applications 4, eds. C. C. Leznoff and A. B. P. Lever (VCH, New York, 1996) p. 1. Google Scholar
J. P. Collmanet al., J. Am. Chem. Soc. 106, 3500 (1984), DOI: 10.1021/ja00324a018. Crossref, Web of Science, Google Scholar
J. P. Collmann and H. J. Arnold, Acc. Chem. Res. 26, 586 (1993), DOI: 10.1021/ar00035a004. Crossref, Web of Science, Google Scholar
A. Capobianchiet al., Inorg. Chem. 33, 4635 (1994), DOI: 10.1021/ic00099a013. Crossref, Web of Science, Google Scholar
H. Bertagnolliet al., Inorg. Chem. 36, 6397 (1997), DOI: 10.1021/ic970653p. Crossref, Web of Science, Google Scholar
F. A. Cottonet al., Science 145, 1305 (1964), DOI: 10.1126/science.145.3638.1305. Crossref, Web of Science, Google Scholar
F. A. Cotton, Inorg. Chem. 4, 334 (1965), DOI: 10.1021/ic50025a016. Crossref, Web of Science, Google Scholar
U. Schlick, PhD Thesis. Universität Tübingen (1996) . Google Scholar