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Synthesis of alkylthio substituted pyridoporphyrazines and their photophysicochemical properties

Department of Sustainable Engineering, College of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan

Academic Major of Applied Molecular Chemistry, Graduate School of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan

E-mail Address: sakamoto.keiichi@nihon-u.ac.jp

Corresponding author, tel: +81 47-474-2554, fax: +81 47-474-9759.

SPP full member in good standing

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Shouta Watabiki

Academic Major of Applied Molecular Chemistry, Graduate School of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan

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Satoru Yoshino

Department of Sustainable Engineering, College of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan

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, and

Tomoe Komoriya

Department of Sustainable Engineering, College of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan

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https://doi.org/10.1142/S1088424617500626Cited by:2 (Source: Crossref)

Abstract

Phthalocyanine and their related compounds are utilized as various applications, such as photosensitizing agents for photodynamic therapy of cancer. In this study, zinc bis(thiodidecylbenzo)-bis(pyrido)porphyrazines, especially zinc bis(1,4-didecylthiobenzo)-bis(3,4-pyrido)porphyrazine and zinc bis(1,4-didecylthiobenzo)-bis(2,3-pyrido)porphyrazine were synthesized. Quaternation of the pyridine nitrogen in these provides an amphiphilic property. Photoexcited triplet lifetime of synthesized and quaternized zinc bis(1,4-didecylthiobenzo)-bis(3,4-pyrido)porphyrazine and zinc bis(1,4-didecylthiobenzo)-bis(2,3-pyrido)porphyrazine were reported using laser-flash photolysis and singlet oxygen quantum yields by the 1,3-diphenylisobenzofurne method.

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Vol. 21, No. 10

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History

Received 12 September 2017

Accepted 19 October 2017

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This is an open access article published by World Scientific Publishing and distributed under the terms of the Creative Commons Attribution (CC BY) 4.0 License, which permits use, distribution and reproduction in any medium, provided the original author(s) and source are credited.

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Synthesis of alkylthio substituted pyridoporphyrazines and their photophysicochemical properties

Abstract

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