Effect of spacer layer on enhancement and quenching of photoluminescence by surface plasmon
Abstract
Metal nanoparticles have the ability to localize and strongly enhance the incident electromagnetic field due to the surface plasmon polariton. The coupling between AuNPs and ZnO thin films affects their emission properties. In this study, we prepared the ZnO/Al2O3/AuNPs multilayer films, and investigated the effect of spacer layer on enhancement and quenching of photoluminescence by surface plasmon. The emission intensities of the thin films vary when Al2O3 space layer with different thickness was embedded in the ZnO/Au films, consistent with theoretical predictions. The photoluminescence modulation is also made via controlling the polarization of the excitation source. The photoluminescence anisotropy of these systems shows that enhanced photoluminescence can be achieved through coupling of the emission from ZnO with the surface plasmon resonance of AuNPs.