No Access

Microwave-assisted immobilization of metallophthalocyanines in mesoporous channels of MCM-41

Mahtab Pirouzmand

Department of Chemistry, Shahid Beheshti University, Tehran 1983963113, Iran

Search for more papers by this author

Mostafa M. Amini

Department of Chemistry, Shahid Beheshti University, Tehran 1983963113, Iran

Corresponding author.

Search for more papers by this author

, and

Nasser Safari

Department of Chemistry, Shahid Beheshti University, Tehran 1983963113, Iran

Corresponding author, fax: +98 21-22431663.

SPP full member in good standing.

Search for more papers by this author

https://doi.org/10.1142/S1088424607000151Cited by:8 (Source: Crossref)

Abstract

Metallophthalocyanines have been assembled in MCM-41 channels by microwave irradiation of a mixture of ion-exchanged MCM-41, and 1,2-dicyanobenzene under solvent-free conditions in a considerably short period of time. The prepared materials have been characterized by diffuse reflectance UV-vis spectroscopy, X-ray powder diffraction XRD, differential scanning calorimetry DSC, and Brunauer-Emmett-Teller BET nitrogen adsorption desorption techniques. The X-ray diffraction and Brunauer-Emmett-Teller results showed that the textural properties of MCM-41 were preserved during microwave irradiation.

Keywords:

Most comprehensive & up-to-date research on PORPHYRINS
Handbook of Porphyrin Science now available in 46 volumes

References

J. J. Spivey (ed.) , Catalysis (Specialist Periodical Reports S.) 18 ( Royal Society of Chemistry , 2005 ) . Google Scholar
S. D. Jackson , J. Hargreaves and D. Lennon (eds.) , Catalysis in Application ( Royal Society of Chemistry , 2003 ) . Google Scholar
G. B. Shul'pin , Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes (Catalysis by Metal Complexes) ( Kluwer , 2002 ) . Google Scholar
K. M. Kadish , K. M. Smith and R. Guilard (eds.) , The Porphyrin Handbook 19 ( Academic Press , 2003 ) . Google Scholar
D. Wöhrleet al., J. Porphyrins Phthalocyanines 8, 1020 (2004). Link, Web of Science, Google Scholar
J. R. Darwentet al., Coord. Chem. Rev. 44, 83 (1982), DOI: 10.1016/S0010-8545(00)80518-4. Crossref, Web of Science, Google Scholar
V. I. Iliev and A. Ileva, J. Mol. Catal. A. 103, 147 (1995). Crossref, Web of Science, Google Scholar
A. B. Sorokin, S. Mangermatin and C. Pergrale, J. Mol. Catal. A 182, 267 (2002). Web of Science, Google Scholar
F. Laeri et al. (eds.) , Host-guest systems based on nanoporous crystals ( Wiley-VCH , 2003 ) . Crossref, Google Scholar
G. Schulz-Ekloff, D. Wöhrle and R. A. Schoonheydt, Microporous Mesoporous Mater. 51, 91 (2002), DOI: 10.1016/S1387-1811(01)00455-3. Crossref, Web of Science, Google Scholar
J. S. Becket al., J. Am. Chem. Soc. 114, 10834 (1992), DOI: 10.1021/ja00053a020. Crossref, Web of Science, Google Scholar
Y. Tanamuraet al., Nano Lett. 1, 387 (2001), DOI: 10.1021/nl015539p. Crossref, Web of Science, Google Scholar
S. Ernst and M. Selle, Microporous Mesoporous Mater. 27, 355 (1999), DOI: 10.1016/S1387-1811(98)00268-6. Crossref, Web of Science, Google Scholar
Y. Zhuet al., Colloids Surf. A 220, 131 (2003), DOI: 10.1016/S0927-7757(03)00069-4. Crossref, Web of Science, Google Scholar
I. Honma and H. S. Zhou, Chem. Mater. 10, 103 (1998), DOI: 10.1021/cm970243z. Crossref, Web of Science, Google Scholar
M. Ganschow, D. Wöhrle and G. Schulz-Ekloff, J. Porphyrins Phthalocyanines 3, 299 (1999). Link, Web of Science, Google Scholar
M. Warket al., Ber. Bunsenges. Phys. Chem. 102, 1548 (1998). Crossref, Web of Science, Google Scholar
R. Hoppeet al., Microporous Mater. 8, 267 (1997). Crossref, Google Scholar
P. Karandikaret al., Appl. Catal. A 257, 133 (2004). Crossref, Web of Science, Google Scholar
E. Armengolet al., Appl. Catal. A 181, 305 (1999). Crossref, Web of Science, Google Scholar
P. T. Taney and T. J. Pinnavaia, Chem. Mater. 8, 2068 (1996). Web of Science, Google Scholar
S. Vetrivel and A. Pandurangan, J. Mol. Catal. A 227, 269 (2005). Crossref, Web of Science, Google Scholar
A. Nematiet al., J. Catal. 205, 7 (2002). Web of Science, Google Scholar
E. P. Barrett, L. G. Joyner and P. P. Halenda, J. Am. Chem. Soc. 73, 373 (1951), DOI: 10.1021/ja01145a126. Crossref, Web of Science, Google Scholar
J. P. Ferrariset al., J. Incl. Phenom. Mol. Recog. 14, 163 (1992), DOI: 10.1007/BF01029664. Crossref, Web of Science, Google Scholar
R. M. Christie and D. D. Deans, J. Chem. Soc. Perkin Trans. 2, 193 (1989). Google Scholar
M. Kasha, H. R. Rawls and M. A. El-Bayoumi, Pure Appl. Chem. 11, 371 (1965), DOI: 10.1351/pac196511030371. Crossref, Google Scholar
S. Brunauer, P. H. Emmett and E. Teller, J. Am. Chem. Soc. 60, 309 (1938), DOI: 10.1021/ja01269a023. Crossref, Web of Science, Google Scholar
G. Leofarrtiet al., Catal. Today 41, 207 (1998). Web of Science, Google Scholar
W. Kaleta and K. Nowinska, Chem. Commun. 536 (2001). Google Scholar
Z. Mehraban and F. Farzaneh, Microporous Mesoporous Mater. 88, 84 (2006), DOI: 10.1016/j.micromeso.2005.09.002. Crossref, Web of Science, Google Scholar
Y. Rohlfinget al., Stud. Surf. Sci. Catal. 142, 1074 (2002). Google Scholar
V. Radha Raniet al., Catal. Commun. 6, 531 (2005). Crossref, Web of Science, Google Scholar
L. M. Gonzalezet al., Tetrahedron Lett. 47, 6465 (2006), DOI: 10.1016/j.tetlet.2006.06.137. Crossref, Web of Science, Google Scholar