ArticlesNo Access

Use of chemical kinetics for the description of metal porphyrin reactivity

G. A. Krestov Institute of the Solution Chemistry of Russian Academy of Sciences, Akademicheskaya str. 1, Ivanovo 153045, Russia

SPP full member in good standing.

Search for more papers by this author

Mariya E. Klyueva

G. A. Krestov Institute of the Solution Chemistry of Russian Academy of Sciences, Akademicheskaya str. 1, Ivanovo 153045, Russia

Ivanovo State University of Chemistry and Technology, Engel's str. 7, Ivanovo 153000, Russia

Search for more papers by this author

Elena Yu. Tyulyaeva

G. A. Krestov Institute of the Solution Chemistry of Russian Academy of Sciences, Akademicheskaya str. 1, Ivanovo 153045, Russia

Corresponding author.

Search for more papers by this author

, and

Nataliya G. Bichan

G. A. Krestov Institute of the Solution Chemistry of Russian Academy of Sciences, Akademicheskaya str. 1, Ivanovo 153045, Russia

Search for more papers by this author

https://doi.org/10.1142/S1088424612500769Cited by:6 (Source: Crossref)

Abstract

The results of use of chemical kinetics receptions, approaches and methods for the study of porphyrins and their metal complexes reactivity are discussed on an example of oxidation, acid-basic, and catalytic reactions of rhodium, palladium, and rhenium complexes of porphyrin in liquid solutions. The peculiarity of the porphyrin reaction rates is analyzed in a brief context of general provisions of the chemical kinetics. The opportunity to use the quasistationarity principle at the definition of the kinetic equation of the reactions with participation of metal porphyrins is shown. The transition from the process kinetic description to consideration of its mechanism is explored.

Keywords:

Most comprehensive & up-to-date research on PORPHYRINS
Handbook of Porphyrin Science now available in 46 volumes

References

Meites L. An Inrtoduction to Chemical Equilbrium and Kinetics, Department of Chemistry Clarkson College of Technology, 1981; [L. Meites. Vvedenie v kurs khimicheskoj termodinamiki I kineteki. M.: Mir. 1984. 480 s. In Russian] . Google Scholar
Practical Chemical Kinetics. Chemical Kinetics in Problems with Decisions, Melnikov M. (Ed.) Publishing house of the Moscow State University, Publishing house of the St.-Petersburg State University: 2006; pp 592 . Google Scholar
S. Balieuaet al., J. Porphyrins Phthalocyanines 12, 1223 (2008). Link, Web of Science, Google Scholar
A. Y. Lebedeva, Th. Troxlerb and S. A. Vinogradov, J. Porphyrins Phthalocyanines 12, 1261 (2008), DOI: 10.1142/S1088424608000480. Link, Web of Science, Google Scholar
B. O. Agboolaet al., J. Porphyrins Phthalocyanines 12, 1289 (2008), DOI: 10.1142/S1088424608000674. Link, Web of Science, Google Scholar
T. Kojimaet al., J. Porphyrins Phthalocyanines 13, 14 (2009), DOI: 10.1142/S1088424609000164. Link, Web of Science, Google Scholar
G. T. Ruiz, A. G. Lappin and G. Ferraudi, J. Porphyrins Phthalocyanines 14, 69 (2010), DOI: 10.1142/S1088424610001751. Link, Web of Science, Google Scholar
A. Romeo, M. A. Castriciano and L. M. Scolaro, J. Porphyrins Phthalocyanines 14, 713 (2010), DOI: 10.1142/S1088424610002586. Link, Web of Science, Google Scholar
M. Ghadamgahi and D. Ajloo, J. Porphyrins Phthalocyanines 15, 240 (2011), DOI: 10.1142/S1088424611003215. Link, Web of Science, Google Scholar
L. Valkovaet al., Biosens. Bioelectron. 20, 1177 (2004), DOI: 10.1016/j.bios.2004.06.047. Crossref, Web of Science, Google Scholar
M. Bouvetet al., J. Porphyrins Phthalocyanines 13, 84 (2009), DOI: 10.1142/S108842460900019X. Link, Web of Science, Google Scholar
F. Mandojet al., J. Porphyrins Phthalocyanines 12, 19 (2008), DOI: 10.1142/S1088424608000042. Link, Web of Science, Google Scholar
C. Capar, K. E. Thomas and A. Ghosh, J. Porphyrins Phthalocyanines 12, 964 (2008), DOI: 10.1142/S1088424608000340. Link, Web of Science, Google Scholar
Tyulyaeva EYu, Kosareva OV, Klyueva ME and Lomova TN. Zh. Neorg. Khim. 2008; 53: 1504–1509 [Russ. J. Inorg. Chem. 2008; 53: 1405–1409] . Google Scholar
M. Yu. Tipugina and T. N. Lomova, Zh. Neorg. Khim. 49, 1285 (2004). Google Scholar
Suslova EE and Lomova TN. Coord. Khim. 2006; 32: 163–173 [Russ. J. Coord. Chem. 2006; 32: 155–165] . Google Scholar
Lomova TN, Mozhzhykhina EG, Danilova EA and Islyaikin MK. Zh. Phys. Khim. 2009; 83: 1877–1883 [Rus. J. Phys. Chem. 2009; 83: 1694–1700] . Google Scholar
T. N. Lomova, L. P. Shormanova and B. D. Berezin, Zh. Neorg. Khim. 32, 2489 (1987). Google Scholar
A. S. Semeikin, Proceedings of XXIX Session of the Russian Workshop on the Chemistry of Porphyrins and Their Analogues (2006) p. 19. Google Scholar
T. N. Lomova, E. Yu. Tyulyaeva and M. E. Klyueva, Palladium: Compounds, Production and Applications, ed. K. M. Brady (Nova Science Publishers, Inc, New York, 2010) pp. 285–306. Google Scholar
T. N. Lomovaet al., Zh. Obshch. Khim. 59, 2317 (1989). Google Scholar
Yu. S. Avlasevichet al., J. Porphyrins Phthalocyanines 10, 425 (2006). Google Scholar
M. I. Vinnik, Uspehy Khim. 35, 1922 (1966). Google Scholar
T. N. Lomova, E. Yu. Tyulyaeva and M. Yu. Tipugina, Advances in Porphyrin Chemistry 4, ed. O. A. Golubchikov (St-Petersburg's State University, 2004) pp. 147–160. Google Scholar
Tyulyaeva EYu, Lomova TN and Andrianova LG. Zh. Neorg. Khim. 2001; 46: 432–437 [Russ. J. Inorg. Chem. 2001; 46: 371] . Google Scholar
Fialkov YuA. The Solvent as Tool of Control of Chemical Process. Knowledge. New in a Life, a Science, Technics. A Series. "Chemistry", Vol. 6, 1988; pp 45 . Google Scholar
N. Carnieri and A. Harriman, Inorg. Chim. Acta. 62, 103 (1982), DOI: 10.1016/S0020-1693(00)88485-6. Crossref, Web of Science, Google Scholar
G. H. Brownet al., J. Am. Chem. Soc. 97, 5385 (1975), DOI: 10.1021/ja00852a011. Crossref, Web of Science, Google Scholar
Deryabkina EV. Candidate's Dissertation in Chemistry, Ivanovo, 2001 . Google Scholar
J. P. Collmanet al., J. Am. Chem. Soc. 106, 5151 (1984), DOI: 10.1021/ja00330a020. Crossref, Web of Science, Google Scholar