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Photophysical and photochemical properties of fluoroether-substituted zinc(II) and titanium(IV) phthalocyanines

TUBITAK, Marmara Research Center, Materials Institute, P.O. Box 21, 41470 Gebze-Kocaeli, Turkey

E-mail Address: ilke.gurol@tubitak.gov.tr

Correspondence to: Ilka Gürol, TUBITAK, Marmara Research Center, Materials Institute, Barış Mah., Dr. Zeki Acar Cad., No 1, 41470 Gebze-Kocaeli, Turkey. Tel: +90 262 677 30 31; fax: +90 262 641 23 09

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Gülay Gümüş

TUBITAK, Marmara Research Center, Materials Institute, P.O. Box 21, 41470 Gebze-Kocaeli, Turkey

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Deniz Kutlu Tarakci

TUBITAK, Marmara Research Center, Materials Institute, P.O. Box 21, 41470 Gebze-Kocaeli, Turkey

Department of Chemistry, Gebze Technical University, Gebze, 41400, Kocaeli, Turkey

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Ömer Güngör

Department of Chemistry, Gebze Technical University, Gebze, 41400, Kocaeli, Turkey

Department of Chemistry Technology, Kocaeli University, Advance Vocational School of Hereke Omer Ismet, Uzunyol, 41800, Kocaeli, Turkey

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Mahmut Durmuş

Department of Chemistry, Gebze Technical University, Gebze, 41400, Kocaeli, Turkey

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, and

Vefa Ahsen

Department of Chemistry, Gebze Technical University, Gebze, 41400, Kocaeli, Turkey

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https://doi.org/10.1142/S1088424618500074Cited by:7 (Source: Crossref)

Abstract

The synthesis and characterization of novel zinc(II) (1a–4a) and oxo-titanium(IV) (1b–4b) phthalocyanine derivatives bearing 1H,1H-nona?uoro-3,6-dioxaheptan-1-ol groups are described for the first time. These phthalocyanines (1a–4a and 1b–4b) were characterized by elemental analysis and different spectroscopic techniques such as UV-vis, $^{1}$ $^{1}$ H NMR, FTIR and mass. Furthermore, the photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen generation and photodegradation) properties of these phthalocyanines were investigated in tetrahydrofuran (THF) solution. The influence of the number of the substituted groups (tetra or octa), position of the substituents (peripheral or non-peripheral) and central metal atom (zinc or titanium) on the photophysical and photochemical properties of these phthalocyanines were evaluated.

This paper is dedicated to Professor Kazuchika Ohta on the occasion of his retirement

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