World Scientific
Skip main navigation

Cookies Notification

We use cookies on this site to enhance your user experience. By continuing to browse the site, you consent to the use of our cookies. Learn More
×

System Upgrade on Tue, May 28th, 2024 at 2am (EDT)

Existing users will be able to log into the site and access content. However, E-commerce and registration of new users may not be available for up to 12 hours.
For online purchase, please visit us again. Contact us at customercare@wspc.com for any enquiries.

Quinoline-annulated porphyrin platinum complexes as NIR emitters

    https://doi.org/10.1142/S1088424619501256Cited by:5 (Source: Crossref)

    The platinum(II) complexes of known quinoline-annulated porphyrins were prepared and spectroscopically characterized. Their optical properties (UV-vis absorption and phosphorescence spectra and phosphorescence lifetimes) were recorded and contrasted against their 2,3-dioxoporphyrin precursor platinum(II) complex. The absorbance and emission spectra (in EtOH glass at 77 K) of the quinoline-annulated porphyrins fall within the NIR optical window of tissue, ranging, depending on the derivative, between 950 and 1200 nm. The much red-shifted optical spectra, when compared to their non-quinoline-annulated precursors, are attributed to the ππ-extension and conformational non-planarity that the annulation causes. The emission yields of the mono-quinoline-annulated derivatives are too low and their lifetimes too short to be practical emitters, but the bis-annulated derivative possesses a practical lifetime and emission yield, suggesting its further exploration, particularly since the methodology toward the solubilization of the quinoline-annulated porphyrins in biological media through derivatization is known.

    Dedicated to Professor Atsuhiro Osuka on the occasion of his 65th birthday.

    Most comprehensive & up-to-date research on PORPHYRINS
    Handbook of Porphyrin Science now available in 46 volumes