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Meso pyridin-4-ylsulfanyl substituted doubly N-confused pentafluorophenyl[26]hexaphyrin

F. Figueira

Department of Chemistry, CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal

LAQV–REQUIMTE, Department of Chemistry, University of Aveiro, 3810–193 Aveiro, Portugal

E-mail Address: ffigueira@ua.pt

Corresponding author.

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Filipe A. Almeida Paz

Department of Chemistry, CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal

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, and

João P. C. Tomé

Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, n^∘ 1, 1049-001 Lisboa, Portugal

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https://doi.org/10.1142/S1088424623500244Cited by:1 (Source: Crossref)

Abstract

In recent years, much attention has been devoted to synthesizing and preparing novel expanded porphyrin architectures. Here we report the selective substitution of the $p$ $p$ -fluorine atoms of meso-hexakis(pentafluorophenyl) $N$ $N$ -confused[26]hexaphyrin with six 4-mercaptopyridine moieties. The preparation methods here described opening an avenue towards the modification and application of these macrocycles in a wide array of applications such as catalysis, sensing, and photonic applications.

Dedicated to Prof. Jonathan L. Sessler on the occasion of his 65th birthday

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