Special Issue on Nanobiomedicine (Part 2); Guest Editors: Feng Wang and Xiaoping ChenNo Access

Interactions Between Graphene Oxide and Rare Earth Metal Ion La(III)

Yuexin Wang

Institute of Polymer Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Gui Lin

Department of Chemistry and The Polymer Research Center, The University of Cincinnati, Cincinnati, OH 45221-0172, USA

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Qing Meng

Institute of Polymer Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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Qian Zhang

Institute of Polymer Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

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, and

James E. Mark

Department of Chemistry and The Polymer Research Center, The University of Cincinnati, Cincinnati, OH 45221-0172, USA

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https://doi.org/10.1142/S1793984414410104Cited by:0 (Source: Crossref)

Abstract

Hybrid graphene oxide (GO) with metal ions have become very promising for many applications including catalyst, thermal conductive paper, magnetic devices, energy storage and electronics. In this paper, GO was mixed with trivalent rare earth ions, LaCl₃ to prepare GO/LaCl₃ hybrid composites. The GO/LaCl₃ hybrid composites were tunable by controlling the ratio of LaCl₃ to GO. The interaction between GO and LaCl₃ includes the coordination of La³⁺ with carboxyl groups at the edges of GO, the coordination of La³⁺ with epoxides and hydroxyls, and the electrostatic force between La³⁺ and aromatic bonds of GO. The La³⁺ preferred the coordination with the oxygen-containing groups of GO sheets first. However, the electrostatic absorption of La³⁺ was the main factor that controls the deposit of GO/LaCl₃ composites. The GO/LaCl₃ hybrid structures were also investigated.

Keywords:

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