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Synthesis of novel PANI-based Ti(IV) phosphosulphosalicylate composite cation exchanger — structural, electrical, and impedance properties

Aditanar College of Arts and Science, Tiruchendur-628 216, Affiliating to Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli-627 012, Tamil Nadu, India

E-mail Address: tamutha1982@gmail.com

Research Scholar, Register Number: 18122022032001.

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K. Jacinth Mispa

Department of Chemistry, Aditanar College of Arts and Science, Tiruchendur-628 216, Affiliating to Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli-627 012, Tamil Nadu, India

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https://doi.org/10.1142/S2010135X21500089Cited by:2 (Source: Crossref)

Abstract

In order to combine the properties of inorganic ion exchanger and conducting organic polymer, a new class of organic–inorganic composite cation exchanger PANI–Ti(IV) phosphosulphosalicylate (PTPSS) was synthesized by intercalating polyaniline (PANI) into Ti(IV) phosphosulphosalicylate (Ti(IV) PSS) using sol–gel chemical route with enhanced properties. PTPSS has been characterized by using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy dispersive X-ray (EDAX), thermo gravimetric analysis (TGA-DTG), and Transmission Electron Microscopy (TEM). Ac electrical conductivity studies were also performed. This material possessed electrical conductivity of $10^{- 3}$ – $10^{- 6}$ ${Scm}^{- 1}$ which falls in the semiconducting range. The frequency (2 × 10⁵ – 1 × 10⁶ Hz) dependent Ac conductivity at room temperature suggests the evidence for the transport mechanism for the conductivity in PTPSS. The structure of the composite cation exchanger extremely supports its conducting behavior.

Keywords:

References

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Vol. 11, No. 01

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History

Received 19 January 2021

Revised 16 February 2021

Accepted 17 February 2021

Published: 18 March 2021

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This is an Open Access article published by World Scientific Publishing Company. It is distributed under the terms of the Creative Commons Attribution 4.0 (CC BY) License which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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Synthesis of novel PANI-based Ti(IV) phosphosulphosalicylate composite cation exchanger — structural, electrical, and impedance properties

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