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A new-type photocatalyst of cadmium sulfide carbon nanotubes (CdS/CNTs) was prepared by the hydrothermal method. This as-prepared CdS/CNTs composite photocatalyst was proved to exhibit an excellent photocatalytic activity for degradation of tetracycline (TC). Specially, the 95%-CdS–5%-CNTs composite photocatalyst played the best degradation rate (81.2%) in 60 min under the visible light irradiation. Moreover, this 95%-CdS–5%-CNTs composite photocatalyst possessed great stability and could be used at least four cycles with almost no loss of photocatalytic efficiency. Furthermore, the as-synthesized CdS/CNTs composite photocatalyst was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-Vis diffused reflectance spectra (UV-Vis), Raman and thermal gravimetry (TG). In addition, the possible mechanism and kinetics of photodegradation of TC with CdS/CNTs photocatalyst was also discussed.
A unique CdS/Fe3O4/rGO composite photocatalyst is successfully synthesized by the microwave method. It displays promising photocatalytic activity towards the photo-degrading of tetracycline (TC) in aqueous solution, the degradation rate of TC is 69% with adding 0.1g CdS/Fe3O4/rGO photocatalyst into 20mg/L tetracycline for 2h under visible light irradiation. Furthermore, the mechanism was systematically investigated by active species trapping experiment. It can be known that e−was the major active species in the photodegradation process and the possible process of charge transfer for CdS/Fe3O4/rGO was proposed based on the experimental results. The as-prepared samples were carefully evaluated by XRD, TEM, XPS, VSM, PL spectra, Raman spectrometer.