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The Raman spectroscopy can be used as a didactic technique in the study of the thermal expansion of Grüneisen parameter and anharmonic behavior of materials. Here, we present exemplary, the lead titanate doped with lanthanum (PLT). However, this method can be used to study various materials. The ferroelectric ceramics have been one of the most studied compounds in the literature both in obtaining the same, as in behavior of chemical and physical properties. The structural PbTiO3 phase may change either by the application of pressure, temperature or concentration, thereby allowing a study of behavior anharmonic of the material [M. R. Joya, J. Barba and P. S. Pizani, J. Appl. Phys.113 (2013) 013512]. This paper gives a brief review of the effect of temperature and pressure on Raman spectra.